Research on two-dimensional FeSiCr/mesoporous MXene composites and their absorption properties

This study constructed FeSiCr/mesoporous MXene composites <i>via</i> electrostatic adsorption, focusing on investigating the regulatory mechanism of MXene pore structure on the material's wave absorption properties. Adjusting the oxidant concentration led to abundant mesoporous voids on the MXene surface, with pores concentrated in the small pore size range, significantly increasing the heterogeneous interfaces and electromagnetic wave transmission pathways within the material. By increasing the mesopore density, the composite's microstructure was optimized, enhancing the interfacial compatibility and the synergistic interaction between the two materials. Combined with FeSiCr, this effectively balanced impedance matching and electromagnetic wave attenuation capabilities. The mesoporous MXene structure obtained by etching with 0.2 mmol L<sup>-1</sup> of oxidizing agent exhibited outstanding S-band performance, achieving an RL<sub>min</sub> value of -66.41 dB. At a matched thickness of 1.85 mm, the effective absorption bandwidth (EAB) reached 10.46 GHz. Results indicate that the outstanding absorptive performance is primarily attributed to the impedance matching characteristics, providing a key technological strategy for developing high-performance, wideband microwave absorbers that are thin, lightweight, and robust.

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Publication Details

Journal
Physical Chemistry Chemical Physics
Published
2025-11-15
DOI
https://doi.org/10.1039/d5cp03903g
Primary Topic
Electromagnetic wave absorption materials
Type
article
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Research on two-dimensional FeSiCr/mesoporous MXene composites and their absorption properties

Zhengxing Li, Honghui Jiang, Quan Fang, Juan Liu et al.
Physical Chemistry Chemical Physics
Electromagnetic wave absorption materials
article

Research on two-dimensional FeSiCr/mesoporous MXene composites and their absorption properties

Zhengxing Li, Honghui Jiang, Quan Fang, Juan Liu, Tongxiang Liang
article en

Abstract

This study constructed FeSiCr/mesoporous MXene composites <i>via</i> electrostatic adsorption, focusing on investigating the regulatory mechanism of MXene pore structure on the material's wave absorption properties. Adjusting the oxidant concentration led to abundant mesoporous voids on the MXene surface, with pores concentrated in the small pore size range, significantly increasing the heterogeneous interfaces and electromagnetic wave transmission pathways within the material. By increasing the mesopore density, the composite's microstructure was optimized, enhancing the interfacial compatibility and the synergistic interaction between the two materials. Combined with FeSiCr, this effectively balanced impedance matching and electromagnetic wave attenuation capabilities. The mesoporous MXene structure obtained by etching with 0.2 mmol L<sup>-1</sup> of oxidizing agent exhibited outstanding S-band performance, achieving an RL<sub>min</sub> value of -66.41 dB. At a matched thickness of 1.85 mm, the effective absorption bandwidth (EAB) reached 10.46 GHz. Results indicate that the outstanding absorptive performance is primarily attributed to the impedance matching characteristics, providing a key technological strategy for developing high-performance, wideband microwave absorbers that are thin, lightweight, and robust.

Physical Chemistry Chemical PhysicsVol. 28(1)
Gannan Normal University (CN), Jiangxi University of Science and Technology (CN)
Openalex Percentile: Top 76%
Electromagnetic wave absorption materials
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