Mixed Co-Mn oxide coatings synthetized by DLI-MOCVD for SOC interconnect a parametric study for composition and homogeneity control

The present study investigates the synthesis of mixed cobalt manganese oxide coating for Solid Oxide Cell (SOC) interconnect application using DLI-MOCVD (Direct Liquid Injection-Metal Oxide Chemical Vapor Deposition). The possibility to control the coating thickness and composition by injecting a mixed solution of Co(acac)<sub>3</sub> and Mn(acac)<sub>3</sub> precursors is demonstrated. Various oxide compositions from Mn<sub>x</sub>Co<sub>1-x</sub>O to Mn<sub>x</sub>Co<sub>3-x</sub>O<sub>4</sub> are synthesized. An acceptable homogeneity in terms of thickness and composition is possible over 25 cm along a tubular reactor which makes this process suitable for industrial application.

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Publication Details

Journal
Scientific Reports
Published
2025-11-14
DOI
https://doi.org/10.1038/s41598-025-23783-5
Primary Topic
Electrical and Thermal Properties of Materials
Type
article
Field-Weighted Citation Impact
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article

Mixed Co-Mn oxide coatings synthetized by DLI-MOCVD for SOC interconnect a parametric study for composition and homogeneity control

Romain Chanson, F. Miserque, Fabien Rouillard, Frédéric Schuster
Scientific Reports
Electrical and Thermal Properties of Materials
article

Mixed Co-Mn oxide coatings synthetized by DLI-MOCVD for SOC interconnect a parametric study for composition and homogeneity control

Romain Chanson, F. Miserque, Fabien Rouillard, Frédéric Schuster
article en

Abstract

The present study investigates the synthesis of mixed cobalt manganese oxide coating for Solid Oxide Cell (SOC) interconnect application using DLI-MOCVD (Direct Liquid Injection-Metal Oxide Chemical Vapor Deposition). The possibility to control the coating thickness and composition by injecting a mixed solution of Co(acac)<sub>3</sub> and Mn(acac)<sub>3</sub> precursors is demonstrated. Various oxide compositions from Mn<sub>x</sub>Co<sub>1-x</sub>O to Mn<sub>x</sub>Co<sub>3-x</sub>O<sub>4</sub> are synthesized. An acceptable homogeneity in terms of thickness and composition is possible over 25 cm along a tubular reactor which makes this process suitable for industrial application.

Scientific ReportsVol. 15(1)
Commissariat à l'Énergie Atomique et aux Énergies Alternatives (FR), Université Paris-Saclay (FR), CEA Paris-Saclay (FR), Institut de Recherche sur les Lois Fondamentales de l'Univers (FR)
Openalex Percentile: Top 66%
Electrical and Thermal Properties of Materials
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