Photoinduced phase transitions and lattice deformation in two-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>NbO</mml:mi> <mml:msub> <mml:mi>X</mml:mi> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> (

We present a comprehensive investigation of light-induced phase transitions and strain in two-dimensional $\mathrm{NbO}{X}_{2}$ ($X=\mathrm{Cl}$, Br, I) using first-principles calculations. In particular, we identify a light-induced ferroelectric-to-paraelectric phase transition in these 2D systems. Furthermore, we demonstrate the possibility of inducing an antiferroelectric-to-paraelectric transition under illumination. Additionally, we find that these 2D systems exhibit significant photostrictive behavior, adding a new functionality to their already notable optical properties. The ability to control and manipulate ferroelectric order in these nanoscale materials through external stimuli, such as light, holds considerable promise for the development of next-generation electronic and optoelectronic devices.

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Publication Details

Journal
Physical Review Materials
Published
2025-11-14
DOI
https://doi.org/10.1103/sbcn-pkv4
Primary Topic
2D Materials and Applications
Type
article
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article

Photoinduced phase transitions and lattice deformation in two-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>NbO</mml:mi> <mml:msub> <mml:mi>X</mml:mi> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> (

Charles Paillard, L. Bellaïche, Carmel Dansou
Physical Review Materials
2D Materials and Applications
article

Photoinduced phase transitions and lattice deformation in two-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>NbO</mml:mi> <mml:msub> <mml:mi>X</mml:mi> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> (

Charles Paillard, L. Bellaïche, Carmel Dansou
article en

Abstract

We present a comprehensive investigation of light-induced phase transitions and strain in two-dimensional $\mathrm{NbO}{X}_{2}$ ($X=\mathrm{Cl}$, Br, I) using first-principles calculations. In particular, we identify a light-induced ferroelectric-to-paraelectric phase transition in these 2D systems. Furthermore, we demonstrate the possibility of inducing an antiferroelectric-to-paraelectric transition under illumination. Additionally, we find that these 2D systems exhibit significant photostrictive behavior, adding a new functionality to their already notable optical properties. The ability to control and manipulate ferroelectric order in these nanoscale materials through external stimuli, such as light, holds considerable promise for the development of next-generation electronic and optoelectronic devices.

Physical Review MaterialsVol. 9(11)
Tel Aviv University (IL), Université Paris-Saclay (FR), CentraleSupélec (FR), University of Arkansas at Fayetteville (US)
Openalex Percentile: Top 73%
2D Materials and Applications
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Photoinduced phase transitions and lattice deformation in two-dimensional <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:mi>NbO</mml:mi> <mml:msub> <mml:mi>X</mml:mi> <mml:mn>2</mml:mn> </mml:msub> </mml:mrow> </mml:math> ( — Charles Paillard, L. Bellaïche, et al. · Physical Review Materials (2025) | TGRS Research Map | TGRS