Spin and lattice dynamics at the spin-reorientation transitions in the rare-earth orthoferrite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Sm</mml:mi> <mml:mrow> <mml:mn>0.55</mml:mn> </mml:mrow> </mml:msub

Linear and nonlinear couplings of magnetic and lattice excitations are at the heart of many fascinating magnetophononic phenomena observed in rare-earth orthoferrites, the distinctive feature of which is the tendency to spin-reorientation transitions. Here we report the results of the experimental study of the spin and lattice dynamics in the Brillouin zone center of the rare-earth orthoferrite ${\mathrm{Sm}}_{0.55}{\mathrm{Tb}}_{0.45}{\mathrm{FeO}}_{3}$ by using polarized infrared reflectivity and Raman scattering spectroscopic techniques. The obtained results were supported by the first-principles calculations, which allowed us to reliably identify the parameters of most infrared- and Raman-active phonons. We reveal the spin-reorientation transitions ${\mathrm{\ensuremath{\Gamma}}}_{4}({G}_{a}{F}_{c})\stackrel{{T}_{1}}{\ensuremath{\leftrightarrows}}{\mathrm{\ensuremath{\Gamma}}}_{24}({\mathrm{G}}_{\mathrm{ac}}{\mathrm{F}}_{\mathrm{ac}})\stackrel{{T}_{2}}{\ensuremath{\leftrightarrows}}{\mathrm{\ensuremath{\Gamma}}}_{2}({\mathrm{G}}_{\mathrm{c}}{\mathrm{F}}_{\mathrm{a}})$ at ${T}_{1}\ensuremath{\simeq}220\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ and ${T}_{2}\ensuremath{\simeq}130\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ and carefully studied the following evolution of Raman scattering on magnetic excitations at these transitions. Notably, the intermediate magnetic structure ${\mathrm{\ensuremath{\Gamma}}}_{24}$ displays an exceptionally broad temperature range $\mathrm{\ensuremath{\Delta}}T={T}_{1}\ensuremath{-}{T}_{2}\ensuremath{\simeq}90\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ in mixed ${\mathrm{Sm}}_{0.55}{\mathrm{Tb}}_{0.45}{\mathrm{FeO}}_{3}$ compared to pure rare-earth orthoferrites. We attribute this broadening of the intermediate phase to the modification of the magnetocrystalline anisotropy as a result of the inhomogeneous magnetic structure caused by the random distribution of rare-earth ${\mathrm{Sm}}^{3+}$ and ${\mathrm{Tb}}^{3+}$ ions. We found neither change in the parameters of Raman-active ${B}_{1g}$ phonons nor the appearance of new phonons induced by spin-reorientation transitions, which have been reported in ${\mathrm{SmFeO}}_{3}$. We assume that our results provide a solid basis for more deeper understanding of magnetophononic phenomena in rare-earth orthoferrites.

Authors

Institutions

Publication Details

Journal
Physical review. B./Physical review. B
Published
2025-11-14
DOI
https://doi.org/10.1103/44m2-sq6k
Citations
1
Primary Topic
Multiferroics and related materials
Type
article
Field-Weighted Citation Impact
0.43

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Spin and lattice dynamics at the spin-reorientation transitions in the rare-earth orthoferrite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Sm</mml:mi> <mml:mrow> <mml:mn>0.55</mml:mn> </mml:mrow> </mml:msub

R. V. Mikhaylovskiy, Anhua Wu, R. M. Dubrovin, V. A. Chernyshev et al.
1 citations
Physical review. B./Physical review. B
Multiferroics and related materials
0.43
article

Spin and lattice dynamics at the spin-reorientation transitions in the rare-earth orthoferrite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Sm</mml:mi> <mml:mrow> <mml:mn>0.55</mml:mn> </mml:mrow> </mml:msub

R. V. Mikhaylovskiy, Anhua Wu, R. M. Dubrovin, V. A. Chernyshev, N. R. Vovk, A. N. Smirnov, V. Yu. Davydov, Н. Н. Новикова, A. M. Kalashnikova, Liangbi Su, I. A. Eliseyev, R. V. Pisarev, A. I. Brulev
article en
1 citations

Abstract

Linear and nonlinear couplings of magnetic and lattice excitations are at the heart of many fascinating magnetophononic phenomena observed in rare-earth orthoferrites, the distinctive feature of which is the tendency to spin-reorientation transitions. Here we report the results of the experimental study of the spin and lattice dynamics in the Brillouin zone center of the rare-earth orthoferrite ${\mathrm{Sm}}_{0.55}{\mathrm{Tb}}_{0.45}{\mathrm{FeO}}_{3}$ by using polarized infrared reflectivity and Raman scattering spectroscopic techniques. The obtained results were supported by the first-principles calculations, which allowed us to reliably identify the parameters of most infrared- and Raman-active phonons. We reveal the spin-reorientation transitions ${\mathrm{\ensuremath{\Gamma}}}_{4}({G}_{a}{F}_{c})\stackrel{{T}_{1}}{\ensuremath{\leftrightarrows}}{\mathrm{\ensuremath{\Gamma}}}_{24}({\mathrm{G}}_{\mathrm{ac}}{\mathrm{F}}_{\mathrm{ac}})\stackrel{{T}_{2}}{\ensuremath{\leftrightarrows}}{\mathrm{\ensuremath{\Gamma}}}_{2}({\mathrm{G}}_{\mathrm{c}}{\mathrm{F}}_{\mathrm{a}})$ at ${T}_{1}\ensuremath{\simeq}220\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ and ${T}_{2}\ensuremath{\simeq}130\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ and carefully studied the following evolution of Raman scattering on magnetic excitations at these transitions. Notably, the intermediate magnetic structure ${\mathrm{\ensuremath{\Gamma}}}_{24}$ displays an exceptionally broad temperature range $\mathrm{\ensuremath{\Delta}}T={T}_{1}\ensuremath{-}{T}_{2}\ensuremath{\simeq}90\phantom{\rule{0.28em}{0ex}}\mathrm{K}$ in mixed ${\mathrm{Sm}}_{0.55}{\mathrm{Tb}}_{0.45}{\mathrm{FeO}}_{3}$ compared to pure rare-earth orthoferrites. We attribute this broadening of the intermediate phase to the modification of the magnetocrystalline anisotropy as a result of the inhomogeneous magnetic structure caused by the random distribution of rare-earth ${\mathrm{Sm}}^{3+}$ and ${\mathrm{Tb}}^{3+}$ ions. We found neither change in the parameters of Raman-active ${B}_{1g}$ phonons nor the appearance of new phonons induced by spin-reorientation transitions, which have been reported in ${\mathrm{SmFeO}}_{3}$. We assume that our results provide a solid basis for more deeper understanding of magnetophononic phenomena in rare-earth orthoferrites.

Physical review. B./Physical review. BVol. 112(17)
Ural Federal University (RU), Chinese Academy of Sciences (CN), Institute of Spectroscopy (RU), Shanghai Institute of Ceramics (CN), Lancaster University (GB), Ioffe Institute (RU)
National Natural Science Foundation of China, Chinese Academy of Sciences, Russian Science Foundation, Ministry of Science and Higher Education of the Russian Federation, Russian Academy of Sciences
Openalex Percentile: Top 34%
Multiferroics and related materials
0.43
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.