Quantum-Geometry–Enabled Terahertz Rectification in the Weyl Semimetal TaP

Noncentrosymmetric crystals can rectify light into a direct current (DC) through the second-order nonlinear response governed by the Berry-curvature dipole (BCD), an effect that becomes particularly efficient for low-energy terahertz (THz) photons. Topological Weyl semimetals (WSMs), with their large Berry curvature near the Weyl points and intrinsically broken inversion symmetry, represent an ideal platform to realize this effect. However, directly experimentally demonstrating a BCD-driven photoresponse in the THz regime remains a significant challenge. Here, we demonstrate room-temperature, junction-free terahertz current rectification in type-I Weyl semimetal tantalum phosphide (TaP) explicitly driven by its intrinsic Berry curvature dipole. We observe that transverse THz polarization generates longitudinal photocurrents with a fast response time (0.96 μs) across a broad bandwidth (0.04-0.53 THz), directly confirming BCD-imposed momentum-space asymmetry and its topological origin. Operating as a room-temperature heterodyne mixer, the TaP device achieves a remarkable 25 dB conversion gain over a 20 GHz instantaneous intermediate-frequency (IF) bandwidth. These results establish Weyl semimetals as a paradigm for topological optoelectronics, where a deeper understanding of quantum geometric effects directly enables the development of high-performance terahertz devices for applications such as 6G wireless communication.

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Publication Details

Journal
ACS Nano
Published
2025-11-13
DOI
https://doi.org/10.1021/acsnano.5c15391
Citations
2
Primary Topic
Topological Materials and Phenomena
Type
article
Field-Weighted Citation Impact
2.49
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article

Quantum-Geometry–Enabled Terahertz Rectification in the Weyl Semimetal TaP

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2 citations
ACS Nano
Topological Materials and Phenomena
2.49
article

Quantum-Geometry–Enabled Terahertz Rectification in the Weyl Semimetal TaP

Lin Wang, Zongju Huo, Hailong Qiu, Kening Xiao, Xuyang Lv, Bojin Zhao, Yiran Tan, Shijian Tian, Weichuan Mo, Mengjie Jiang, Libo Zhang, Xiaohong Chen, Kaixuan Zhang, Bangjian Zhao, Shi Zhang, Bo Peng, Yichong Zhang, Yuanfeng Wen, Yunduo Zhang
article en
2 citations

Abstract

Noncentrosymmetric crystals can rectify light into a direct current (DC) through the second-order nonlinear response governed by the Berry-curvature dipole (BCD), an effect that becomes particularly efficient for low-energy terahertz (THz) photons. Topological Weyl semimetals (WSMs), with their large Berry curvature near the Weyl points and intrinsically broken inversion symmetry, represent an ideal platform to realize this effect. However, directly experimentally demonstrating a BCD-driven photoresponse in the THz regime remains a significant challenge. Here, we demonstrate room-temperature, junction-free terahertz current rectification in type-I Weyl semimetal tantalum phosphide (TaP) explicitly driven by its intrinsic Berry curvature dipole. We observe that transverse THz polarization generates longitudinal photocurrents with a fast response time (0.96 μs) across a broad bandwidth (0.04-0.53 THz), directly confirming BCD-imposed momentum-space asymmetry and its topological origin. Operating as a room-temperature heterodyne mixer, the TaP device achieves a remarkable 25 dB conversion gain over a 20 GHz instantaneous intermediate-frequency (IF) bandwidth. These results establish Weyl semimetals as a paradigm for topological optoelectronics, where a deeper understanding of quantum geometric effects directly enables the development of high-performance terahertz devices for applications such as 6G wireless communication.

ACS NanoVol. 19(46)
Tianjin University of Technology (CN), Chinese Academy of Sciences (CN), Crystal Research (United States) (US), Suzhou Institute of Nano-tech and Nano-bionics (CN), Shanghai Institute of Technical Physics (CN), University of Chinese Academy of Sciences (CN), State Key Laboratory of Crystal Materials
Openalex Percentile: Top 9%
Topological Materials and Phenomena
2.49
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