Multiple superconducting transitions in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Yb</mml:mi> <mml:mrow> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> <mml:mi>x</mml:mi> </mml:mrow> </mml:msub> <mml:msub> <mml:mi

In the Yb-Co-Sn system a Remeika phase ${\mathrm{Yb}}_{3+x}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{13\ensuremath{-}x}$ is found with solid solution extending within $0\ensuremath{\le}x\ensuremath{\le}0.5$. All these compounds crystallize with primitive cubic (space group $Pm\overline{3}n, a\ensuremath{\approx}9.54\phantom{\rule{0.16em}{0ex}}\AA{}$) strongly disordered ${\mathrm{Sc}}_{3}{\mathrm{Ir}}_{4}{\mathrm{Si}}_{13+x}$ type. Stoichiometric ${\mathrm{Yb}}_{3}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{13}$ is a superconductor with critical temperature ${T}_{c}=3.1(2)\phantom{\rule{4pt}{0ex}}\mathrm{K}$, lower- $[{B}_{\mathrm{c}}1=1.90(2)\phantom{\rule{0.16em}{0ex}}\mathrm{mT}]$ and upper $[{B}_{\mathrm{c}}2=2.16(5)\phantom{\rule{0.16em}{0ex}}\mathrm{T}]$ critical fields. The specific-heat jump $\mathrm{\ensuremath{\Delta}}{c}_{p}/\ensuremath{\gamma}{T}_{c}=1.72(9)$ together with the fact that ${B}_{\mathrm{c}}2({T}_{c})$ dependence is described by the Werthamer-Helfand-Hohenberg (WHH) model hint toward a conventional mechanism with a weak electron-phonon coupling. Although a more precise analysis is hampered by the presence of multiple superconducting transitions observed in the specific heat of this Remeika phase, the nonstoichiometric ${\mathrm{Yb}}_{3.2}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{12.8}$ reveals ${T}_{c}=2.4(2)\phantom{\rule{4pt}{0ex}}\mathrm{K}$ and ${B}_{\mathrm{c}}2=4.79(9)\phantom{\rule{0.16em}{0ex}}\mathrm{T}$ exceeding the classical Pauli limit. Strong electron-phonon coupling in this superconductor is confirmed by the high value of the ${\ensuremath{\lambda}}_{\mathrm{AD}}=0.92(2)$ parameter determined from the Allen-Dynes formula. However, the electronic specific heat of ${\mathrm{Yb}}_{3.2}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{12.8}$ follows the exponential law $[{c}_{\mathrm{el}}(T)\ensuremath{\propto}{e}^{\ensuremath{-}\mathrm{\ensuremath{\Delta}}(0)/{k}_{\mathrm{B}}T}]$ and can be described by the $\ensuremath{\alpha}$-model $[\ensuremath{\alpha}\ensuremath{\equiv}\mathrm{\ensuremath{\Delta}}(0)/{k}_{\mathrm{B}}{T}_{c}=2]$ indicating this stannide to be a conventional BCS-superconductor. Both ${\mathrm{Yb}}_{3+x}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{13\ensuremath{-}x}$ ($x=0,0.2$) compounds reveal complex phonon spectra with possible ``rattling'' behavior. They are also found to be metallic systems, some aspects of which can be described by a free-electron-gas model.

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Journal
Physical review. B./Physical review. B
Published
2025-11-12
DOI
https://doi.org/10.1103/xl5c-y798
Primary Topic
Rare-earth and actinide compounds
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article
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article

Multiple superconducting transitions in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Yb</mml:mi> <mml:mrow> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> <mml:mi>x</mml:mi> </mml:mrow> </mml:msub> <mml:msub> <mml:mi

Alexander A. Tsirlin, Roman Gumeniuk, Elena V. Sturm, Andreas Leithe‐Jasper et al.
Physical review. B./Physical review. B
Rare-earth and actinide compounds
article

Multiple superconducting transitions in <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mi>Yb</mml:mi> <mml:mrow> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> <mml:mi>x</mml:mi> </mml:mrow> </mml:msub> <mml:msub> <mml:mi

Alexander A. Tsirlin, Roman Gumeniuk, Elena V. Sturm, Andreas Leithe‐Jasper, Volodymyr Levytskyy, B. Kundys, Meret Orlob
article en

Abstract

In the Yb-Co-Sn system a Remeika phase ${\mathrm{Yb}}_{3+x}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{13\ensuremath{-}x}$ is found with solid solution extending within $0\ensuremath{\le}x\ensuremath{\le}0.5$. All these compounds crystallize with primitive cubic (space group $Pm\overline{3}n, a\ensuremath{\approx}9.54\phantom{\rule{0.16em}{0ex}}\AA{}$) strongly disordered ${\mathrm{Sc}}_{3}{\mathrm{Ir}}_{4}{\mathrm{Si}}_{13+x}$ type. Stoichiometric ${\mathrm{Yb}}_{3}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{13}$ is a superconductor with critical temperature ${T}_{c}=3.1(2)\phantom{\rule{4pt}{0ex}}\mathrm{K}$, lower- $[{B}_{\mathrm{c}}1=1.90(2)\phantom{\rule{0.16em}{0ex}}\mathrm{mT}]$ and upper $[{B}_{\mathrm{c}}2=2.16(5)\phantom{\rule{0.16em}{0ex}}\mathrm{T}]$ critical fields. The specific-heat jump $\mathrm{\ensuremath{\Delta}}{c}_{p}/\ensuremath{\gamma}{T}_{c}=1.72(9)$ together with the fact that ${B}_{\mathrm{c}}2({T}_{c})$ dependence is described by the Werthamer-Helfand-Hohenberg (WHH) model hint toward a conventional mechanism with a weak electron-phonon coupling. Although a more precise analysis is hampered by the presence of multiple superconducting transitions observed in the specific heat of this Remeika phase, the nonstoichiometric ${\mathrm{Yb}}_{3.2}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{12.8}$ reveals ${T}_{c}=2.4(2)\phantom{\rule{4pt}{0ex}}\mathrm{K}$ and ${B}_{\mathrm{c}}2=4.79(9)\phantom{\rule{0.16em}{0ex}}\mathrm{T}$ exceeding the classical Pauli limit. Strong electron-phonon coupling in this superconductor is confirmed by the high value of the ${\ensuremath{\lambda}}_{\mathrm{AD}}=0.92(2)$ parameter determined from the Allen-Dynes formula. However, the electronic specific heat of ${\mathrm{Yb}}_{3.2}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{12.8}$ follows the exponential law $[{c}_{\mathrm{el}}(T)\ensuremath{\propto}{e}^{\ensuremath{-}\mathrm{\ensuremath{\Delta}}(0)/{k}_{\mathrm{B}}T}]$ and can be described by the $\ensuremath{\alpha}$-model $[\ensuremath{\alpha}\ensuremath{\equiv}\mathrm{\ensuremath{\Delta}}(0)/{k}_{\mathrm{B}}{T}_{c}=2]$ indicating this stannide to be a conventional BCS-superconductor. Both ${\mathrm{Yb}}_{3+x}{\mathrm{Co}}_{4}{\mathrm{Sn}}_{13\ensuremath{-}x}$ ($x=0,0.2$) compounds reveal complex phonon spectra with possible ``rattling'' behavior. They are also found to be metallic systems, some aspects of which can be described by a free-electron-gas model.

Physical review. B./Physical review. BVol. 112(17)
Max Planck Society (DE), Institut de Physique et Chimie des Matériaux de Strasbourg (FR), Institut für Technische und Angewandte Physik (Germany) (DE), TU Bergakademie Freiberg (DE), Université de Strasbourg (FR), Ludwig-Maximilians-Universität München (DE), Leipzig University (DE)
Openalex Percentile: Top 78%
Rare-earth and actinide compounds
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