Precision calculation of the bound-electron <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mi>g</mml:mi> </mml:math> factor in molecular hydrogen ions
We calculate the bound-electron $g$ factor for a wide range of rovibrational states in the ground $(1s\ensuremath{\sigma})$ electronic state of the molecular hydrogen ions ${\mathrm{H}}_{2}^{+}$ and ${\mathrm{HD}}^{+}$. Relativistic and QED corrections of orders up to ${\ensuremath{\alpha}}^{5}$ are taken into account. All contributions are calculated in a nonrelativistic QED framework, except for relativistic corrections of order ${(Z\ensuremath{\alpha})}^{4}$ and above, which are obtained by calculating the relativistic $g$ factor using a precise minmax finite element solution of the two-center Dirac equation. A relative accuracy of $(4--5)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}11}$ is achieved for the scalar $g$\ensuremath{-}factor component, which represents an improvement by more than three orders of magnitude over previous calculations. These results are useful for internal state identification and rovibraional spectroscopy of single molecular hydrogen ions in Penning traps, and open an avenue toward precision tests of QED.
Authors
- Ossama Kullie (ORCID: https://orcid.org/0000-0003-3931-7235)
- Hugo D. Nogueira (ORCID: https://orcid.org/0000-0003-1663-5476)
- Jean‐Philippe Karr (ORCID: https://orcid.org/0000-0003-2082-0914)
Institutions
- University of Kassel (DE)
- Université Paris-Saclay (FR)
- Laboratoire Kastler Brossel (FR)
Publication Details
- Journal
- Physical review. A/Physical review, A
- Published
- 2025-11-12
- DOI
- https://doi.org/10.1103/cb1q-fhk5
- Primary Topic
- Atomic and Molecular Physics
- Type
- article
- Field-Weighted Citation Impact
- 0.00