Precision calculation of the bound-electron <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mi>g</mml:mi> </mml:math> factor in molecular hydrogen ions

We calculate the bound-electron $g$ factor for a wide range of rovibrational states in the ground $(1s\ensuremath{\sigma})$ electronic state of the molecular hydrogen ions ${\mathrm{H}}_{2}^{+}$ and ${\mathrm{HD}}^{+}$. Relativistic and QED corrections of orders up to ${\ensuremath{\alpha}}^{5}$ are taken into account. All contributions are calculated in a nonrelativistic QED framework, except for relativistic corrections of order ${(Z\ensuremath{\alpha})}^{4}$ and above, which are obtained by calculating the relativistic $g$ factor using a precise minmax finite element solution of the two-center Dirac equation. A relative accuracy of $(4--5)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}11}$ is achieved for the scalar $g$\ensuremath{-}factor component, which represents an improvement by more than three orders of magnitude over previous calculations. These results are useful for internal state identification and rovibraional spectroscopy of single molecular hydrogen ions in Penning traps, and open an avenue toward precision tests of QED.

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Publication Details

Journal
Physical review. A/Physical review, A
Published
2025-11-12
DOI
https://doi.org/10.1103/cb1q-fhk5
Primary Topic
Atomic and Molecular Physics
Type
article
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article

Precision calculation of the bound-electron <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mi>g</mml:mi> </mml:math> factor in molecular hydrogen ions

Ossama Kullie, Hugo D. Nogueira, Jean‐Philippe Karr
Physical review. A/Physical review, A
Atomic and Molecular Physics
article

Precision calculation of the bound-electron <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mi>g</mml:mi> </mml:math> factor in molecular hydrogen ions

Ossama Kullie, Hugo D. Nogueira, Jean‐Philippe Karr
article en

Abstract

We calculate the bound-electron $g$ factor for a wide range of rovibrational states in the ground $(1s\ensuremath{\sigma})$ electronic state of the molecular hydrogen ions ${\mathrm{H}}_{2}^{+}$ and ${\mathrm{HD}}^{+}$. Relativistic and QED corrections of orders up to ${\ensuremath{\alpha}}^{5}$ are taken into account. All contributions are calculated in a nonrelativistic QED framework, except for relativistic corrections of order ${(Z\ensuremath{\alpha})}^{4}$ and above, which are obtained by calculating the relativistic $g$ factor using a precise minmax finite element solution of the two-center Dirac equation. A relative accuracy of $(4--5)\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}11}$ is achieved for the scalar $g$\ensuremath{-}factor component, which represents an improvement by more than three orders of magnitude over previous calculations. These results are useful for internal state identification and rovibraional spectroscopy of single molecular hydrogen ions in Penning traps, and open an avenue toward precision tests of QED.

Physical review. A/Physical review, AVol. 112(5)
University of Kassel (DE), Université Paris-Saclay (FR), Laboratoire Kastler Brossel (FR)
Openalex Percentile: Top 73%
Atomic and Molecular Physics
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Precision calculation of the bound-electron <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mi>g</mml:mi> </mml:math> factor in molecular hydrogen ions — Ossama Kullie, Hugo D. Nogueira, et al. · Physical review. A/Physical review, A (2025) | TGRS Research Map | TGRS