Scalable manganese-electrocatalytic three-component heteroarene azidoalkylation <i>via</i> a polarity-reversing radical cascade
The first example of an Mn-catalyzed electrochemical three-component Minisci-type reaction of N-heteroarenes with unactivated alkenes and NaN 3 via a polarity-reversal pathway is described.
Authors
- Peng Xiong (ORCID: https://orcid.org/0000-0001-7310-8678)
- Er‐Jun Hao (ORCID: https://orcid.org/0000-0001-5821-8465)
- Xin Liu (ORCID: https://orcid.org/0000-0001-6126-7129)
- Zhong-Xu Zhang
- Hai‐Ming Guo (ORCID: https://orcid.org/0000-0003-0629-4524)
- Rong Wang (ORCID: https://orcid.org/0000-0003-1962-0165)
- Qi-Liang Yang
- Ye Zhu (ORCID: https://orcid.org/0000-0002-5281-1951)
- Shu-Xian Liu
- Zhuo Qiao
Institutions
- Xiamen University (CN)
- Henan Normal University (CN)
Publication Details
- Journal
- Organic Chemistry Frontiers
- Published
- 2025-11-12
- DOI
- https://doi.org/10.1039/d5qo01302j
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00