Impact-generated magnetite in Chang’e-5 soil as a potential recorder of lunar magnetism

Abstract Magnetite is a principal paleomagnetic recorder on Earth, but lunar magnetism is thought to be dominated by metallic iron and Fe-Ni alloys, with magnetite rare and typically sub-micrometer within troilite. We identify nanometer- to micrometer-scale magnetite in pentlandite-troilite assemblages from a Chang’e-5 regolith breccia. Magnetite occurs at and within pentlandite, locally enclosing pentlandite nanoinclusions, implying a formation pathway distinct from troilite-hosted occurrences. Textures and compositions indicate sequential crystallization from an impact-generated Fe-Ni-S-O melt: rapid pentlandite growth along troilite margins followed by magnetite nucleation at sulfide-silicate interfaces. The lunar low oxygen fugacity stabilizes Fe 2+ -enriched magnetite, unlike terrestrial analogues. High crystallinity and single-domain to single-vortex states indicate strong remanence stability, making these grains reliable recorders of the contemporaneous lunar magnetic fields. These results broaden the inventory of lunar magnetic carriers, demonstrate impact-driven magnetite formation under lunar redox conditions, and motivate use of magnetite to refine the Moon’s magnetic history.

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Publication Details

Journal
Communications Earth & Environment
Published
2025-11-10
DOI
https://doi.org/10.1038/s43247-025-02868-z
Citations
2
Primary Topic
Planetary Science and Exploration
Type
article
Field-Weighted Citation Impact
2.31

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article

Impact-generated magnetite in Chang’e-5 soil as a potential recorder of lunar magnetism

Lin Gu, Xiaojing Sha, Qiuli Li, ShiQi Cheng et al.
2 citations
Communications Earth & Environment
Planetary Science and Exploration
2.31
article

Impact-generated magnetite in Chang’e-5 soil as a potential recorder of lunar magnetism

Lin Gu, Xiaojing Sha, Qiuli Li, ShiQi Cheng, Lixin Gu, Xu Tang, Zheng Gong, Yongxin Pan, Qianqian Lan, Rafal E. Dunin–Borkowski, Yuqin Wang, Jinhua Li, Qinghua Zhang, Chen Li, Jian Wang, Yang Li, Chaoqun Zhang, Peiyu Liu, Andrew P. Roberts, Weiwei Wu, Gang Li, Jiawei Liu, Yi Chen
article en
2 citations

Abstract

Abstract Magnetite is a principal paleomagnetic recorder on Earth, but lunar magnetism is thought to be dominated by metallic iron and Fe-Ni alloys, with magnetite rare and typically sub-micrometer within troilite. We identify nanometer- to micrometer-scale magnetite in pentlandite-troilite assemblages from a Chang’e-5 regolith breccia. Magnetite occurs at and within pentlandite, locally enclosing pentlandite nanoinclusions, implying a formation pathway distinct from troilite-hosted occurrences. Textures and compositions indicate sequential crystallization from an impact-generated Fe-Ni-S-O melt: rapid pentlandite growth along troilite margins followed by magnetite nucleation at sulfide-silicate interfaces. The lunar low oxygen fugacity stabilizes Fe 2+ -enriched magnetite, unlike terrestrial analogues. High crystallinity and single-domain to single-vortex states indicate strong remanence stability, making these grains reliable recorders of the contemporaneous lunar magnetic fields. These results broaden the inventory of lunar magnetic carriers, demonstrate impact-driven magnetite formation under lunar redox conditions, and motivate use of magnetite to refine the Moon’s magnetic history.

Communications Earth & EnvironmentVol. 6(1)
Australian National University (AU), Forschungszentrum Jülich (DE), Chinese Academy of Sciences (CN), Ernst Ruska Centre (DE), University of Saskatchewan (CA), Institute of Geology and Geophysics (AZ), Carl Zeiss (United States) (US), Institute of Geology and Geophysics (CN), Institute of Geochemistry (CN), Institute of High Energy Physics (CN), Institute of Physics (CN), National Laboratory for Superconductivity (CN), University of Chinese Academy of Sciences (CN), Canadian Light Source (Canada) (CA), Nanjing University (CN), Tsinghua University (CN)
Canadian Light Source, National Natural Science Foundation of China, Canadian Institutes of Health Research, Natural Sciences and Engineering Research Council of Canada, Western Economic Diversification Canada
Openalex Percentile: Top 10%
Planetary Science and Exploration
2.31
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