Development and Characterization of Hydrogen Peroxide Gels with Organic Gelling Agents for Use with Microencapsulated Fuels

Hydrogen peroxide is a promising oxidizer and monopropellant for space propulsion, offering a green alternative to conventional propellants. In combination with microencapsulated hydrocarbon fuels, a new type of monopropellant can be formed that unites the high specific impulse of a bipropellant with the efficient hardware of a monopropellant. However, the stabilization of these microcapsule/hydrogen peroxide mixtures is problematic as they tend to separate after a short period of time. This work uses organic gelling agents to stabilize these mixtures by creating hydrogen peroxide gels. For this, the compatibility of hydrogen peroxide with several gelling agents was investigated and found to be suitable. Next, the dispersion stability of microcapsule/gel dispersions was examined and showed no sign of destabilization over four weeks or at high accelerations at 50× g in the centrifuge, even with gelling agent concentrations as low as 0.1%. A formulation with a polyacrylic acid-based gelling agent at a concentration of 0.3% showed favorable characteristics and good processability. Together with a subsequent rheological characterization of the gels, these results are critical for the further development of the fuel-filled microcapsule/hydrogen peroxide monopropellant. The hydrogen peroxide gel formulations developed in this study could also have potential applications beyond the scope of this work.