Chemical and Physical Characterisation of Microplastics Present on Beaches of the Cantabrian Coast, Bay of Biscay (Spain)

We investigated the presence, chemical/morphological characteristics, and distribution of microplastics (MPs, 1–5 mm) in three beaches located at the southeast of the Bay of Biscay, an area where this kind of study is scarce. Sampling was carried out in March 2022/2023 and October 2023/2024. The microplastics found were chemically characterised by Raman spectroscopy and morphologically described (size, shape, and colour) by visual observation. A total of 836 MPs were found, with Atxabiribil beach showing the highest mean concentrations (15 MPs kg−1), followed by Sonabia (10 MPs kg−1) and Gorliz (3 MPs kg−1). The highest concentrations were recorded in March 2023 and the lowest ones in March 2024, with no clear seasonal trend. Foam, fragments, and pellets were dominant, although filaments, films, and fibres were also found. White MPs were the most abundant, followed by blue and black items. Polyethylene, polypropylene, and polystyrene, in this order, were the most common polymers. In conclusion, we report here valuable information about the abundance and characteristics of MPs in beaches located in an area poorly investigated previously. The results obtained underline the importance of the implementation of regular monitoring campaigns to estimate the impact and consequences that plastic pollution has in our coastal environments.