Natural Resin Nanofilms through Flexible Coordination for Molecular Separation
Abstract Forestry biomass, with its diverse functionalities and abundant resources, holds great potential for the sustainable development of thin‐film technologies. However, high brittleness arising from the rigid structural units of most forestry biomass materials significantly hinders thin‐film processing. We demonstrate the transformation of rosin, a typical brittle forestry resin, into mechanically robust nanofilms with flexible chemical linkages. Carboxylic rosin derivatives solubilized in turpentine, a natural oleoresin solvent, were chemically assembled into nanofilms via interfacial coordination with aqueous metal ions. Tunable metal‐rosin coordination enables precise structural modulation of nanofilms to achieve exceptional stiffness (Young's modulus>120 GPa) while its dynamic nature renders nanofilms high elasticity for pliable integration. The resulting nanofilm composite membranes exhibit durable and efficient molecular sieving during nanofiltration, with pressure resistance up to 20 bar and superior permselectivity. As an emerging form of natural resin, these nanofilms may revolutionize the paradigm of biomass‐based thin films by overcoming brittleness through flexibility.
Authors
- Fengcai Lin (ORCID: https://orcid.org/0009-0008-6021-3872)
- Biao Huang (ORCID: https://orcid.org/0000-0002-5005-6980)
- Lirong Tang
- Zifan Song
- Xingzhong Cao (ORCID: https://orcid.org/0000-0001-5011-5912)
- Meijie Wang (ORCID: https://orcid.org/0009-0008-2000-5438)
- Mingyang Sun (ORCID: https://orcid.org/0000-0003-2728-5117)
- Jiande Lin (ORCID: https://orcid.org/0000-0002-5303-5771)
- Beili Lu (ORCID: https://orcid.org/0000-0002-7957-1986)
- Li Cao (ORCID: https://orcid.org/0000-0002-7087-9431)
- Guanfeng Lin (ORCID: https://orcid.org/0000-0003-3601-9179)
- Jianhua Lv (ORCID: https://orcid.org/0009-0003-2706-5613)
- Qilin Lu (ORCID: https://orcid.org/0000-0002-3152-0303)
- Jinqiu Yuan (ORCID: https://orcid.org/0000-0001-6143-4302)
- Yunzhuo Xu
- Yingpeng Xie (ORCID: https://orcid.org/0000-0002-8745-4165)
- Dai Shi (ORCID: https://orcid.org/0000-0002-6600-4325)
- Zhongyi Jiang (ORCID: https://orcid.org/0000-0002-3813-9943)
- Xinda You (ORCID: https://orcid.org/0009-0004-6489-416X)
- Hanyang Liu
Institutions
- Sinopec (China) (CN)
- Tianjin University of Science and Technology (CN)
- Tianjin University of Technology (CN)
- Tianjin University (CN)
- Xiamen University (CN)
- Chinese Academy of Sciences (CN)
- Minjiang University (CN)
- Zero to Three (US)
- Institute of High Energy Physics (CN)
- Fujian Agriculture and Forestry University (CN)
- King Abdullah University of Science and Technology (SA)
- Fujian University of Technology (CN)
Publication Details
- Journal
- Angewandte Chemie
- Published
- 2025-11-10
- DOI
- https://doi.org/10.1002/ange.202513921
- Primary Topic
- Covalent Organic Framework Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.00