Binuclear Bi(III) Bromide Complexes with 1,1′-(alkane-1,X-diyl)Bis(3,5-dimethyl)Pyridine Dications

Complexes {(3,5-MePy)2(CH2)n}3[Bi2Br9]2 (n = 2 (1), 5 (2)) are obtained by the reaction of bismuth oxide with salts of various doubly charged cations based on 3,5-dimethylpyridine in concentrated HBr, and they are structurally characterized by X-ray diffraction. The features of intermolecular contacts in the crystal structure are considered.

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Journal
Journal of Structural Chemistry
Published
2025-10-01
DOI
https://doi.org/10.1134/s0022476625100087
Primary Topic
Synthesis and characterization of novel inorganic/organometallic compounds
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article
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article

Binuclear Bi(III) Bromide Complexes with 1,1′-(alkane-1,X-diyl)Bis(3,5-dimethyl)Pyridine Dications

Maksim Sokolov, Sergey A. Adonin, Irina A. Shentseva, Andrey N. Usoltsev et al.
Journal of Structural Chemistry
Synthesis and characterization of novel inorganic/organometallic compounds
article

Binuclear Bi(III) Bromide Complexes with 1,1′-(alkane-1,X-diyl)Bis(3,5-dimethyl)Pyridine Dications

Maksim Sokolov, Sergey A. Adonin, Irina A. Shentseva, Andrey N. Usoltsev, Nikita A. Korobeynikov
article en

Abstract

Complexes {(3,5-MePy)2(CH2)n}3[Bi2Br9]2 (n = 2 (1), 5 (2)) are obtained by the reaction of bismuth oxide with salts of various doubly charged cations based on 3,5-dimethylpyridine in concentrated HBr, and they are structurally characterized by X-ray diffraction. The features of intermolecular contacts in the crystal structure are considered.

Journal of Structural ChemistryVol. 66(10)
A.E. Favorsky Irkutsk Institute of Chemistry (RU), Nikolaev Institute of Inorganic Chemistry (RU)
Openalex Percentile: Top 72%
Synthesis and characterization of novel inorganic/organometallic compounds
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