Synthesis of fluorinated phenylene-alkoxybenzothiadiazole polymer (PDTBTBz-2F <sub>anti</sub> ) by DHAP

A new synthesis of PDTBTBz-2F anti was developed via DHAP using a partially biobased monomer. Two pathways were compared by DFT, experiments and OSC tests, benchmarked to Stille coupling, and preliminarily adapted to continuous-flow.

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Journal
Polymer Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5py00957j
Primary Topic
Innovative Microfluidic and Catalytic Techniques Innovation
Type
article
Field-Weighted Citation Impact
0.00

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article

Synthesis of fluorinated phenylene-alkoxybenzothiadiazole polymer (PDTBTBz-2F anti ) by DHAP

David Gendron, Mathieu Mainville, William Dupont, Paul A. Johnson et al.
Polymer Chemistry
Innovative Microfluidic and Catalytic Techniques Innovation
article

Synthesis of fluorinated phenylene-alkoxybenzothiadiazole polymer (PDTBTBz-2F anti ) by DHAP

David Gendron, Mathieu Mainville, William Dupont, Paul A. Johnson, Tristan Marcoux St-Pierre, Mario Leclerc, Louis‐Philippe Boivin
article en

Abstract

A new synthesis of PDTBTBz-2F anti was developed via DHAP using a partially biobased monomer. Two pathways were compared by DFT, experiments and OSC tests, benchmarked to Stille coupling, and preliminarily adapted to continuous-flow.

Polymer ChemistryVol. 16(46)
Cegep de Thetford (CA), Université Laval (CA)
Natural Sciences and Engineering Research Council of Canada, Fonds de recherche du Québec – Nature et technologies
Openalex Percentile: Top 68%
Innovative Microfluidic and Catalytic Techniques Innovation
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