One-pot straightforward access to a cyclometalated acetate platinum( <scp>ii</scp> ) complex exhibiting mechanochromic luminescence
A mononuclear cyclometalated acetate platinum complex (ppy)Pt(Py)(OAc) (1) was prepared using a convenient synthetic approach. The target compound was isolated in three different polymorphic modifications, with variation in the number of asymmetric units per unit cell (<i>Z</i>'). The complex possessed polymorph-dependent luminescence as well as reversible mechanochromism upon a 'grinding-fuming' cycle, resulting in a total of 5 distinct emission spectra for a single molecular structure.
Authors
- Ivan V. Skabitsky (ORCID: https://orcid.org/0000-0002-4374-5024)
- Sergei V. Tatarin (ORCID: https://orcid.org/0000-0002-1503-8189)
- Е. А. Сосунов (ORCID: https://orcid.org/0000-0003-3661-0444)
- Ilya A. Yakushev (ORCID: https://orcid.org/0000-0001-6784-947X)
- Maria V. Panina (ORCID: https://orcid.org/0009-0002-7288-5859)
- A. G. Son (ORCID: https://orcid.org/0009-0006-7107-5714)
Institutions
- Russian Academy of Sciences (RU)
- D. Mendeleyev University of Chemical Technology of Russia (RU)
- NS Kurnakova Institute of General and Inorganic Chemistry (RU)
Publication Details
- Journal
- Dalton Transactions
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5dt01895a
- Primary Topic
- Organic Light-Emitting Diodes Research
- Type
- article
- Field-Weighted Citation Impact
- 0.00