Enhanced electrochemical Cs <sup>+</sup> extraction performance enabled by a MoS <sub>2</sub> /Ni <sub>3</sub> S <sub>2</sub> heterostructure counter electrode

In this work, for the first time, an MoS<sub>2</sub>/Ni<sub>3</sub>S<sub>2</sub> heterostructure (MSNS) was employed as the counter electrode. When combined with an unmodified Cu-PBA working electrode, the equilibrium adsorption capacity reached up to 579.66 mg g<sup>-1</sup> and it demonstrated high Cs<sup>+</sup> selectivity and excellent cycling stability. A detailed study indicated that the exceptional HER/OER catalytic activity of MSNS mitigated polarization and expedited electron transfer, thereby augmenting the electrochemical Cs<sup>+</sup> extraction performance.

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Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc05619e
Primary Topic
Chemical Synthesis and Characterization
Type
article
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article

Enhanced electrochemical Cs + extraction performance enabled by a MoS 2 /Ni 3 S 2 heterostructure counter electrode

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Chemical Communications
Chemical Synthesis and Characterization
article

Enhanced electrochemical Cs + extraction performance enabled by a MoS 2 /Ni 3 S 2 heterostructure counter electrode

Tianlong Deng, Haixia Xing, Jiayin Hu, Yuanyuan Zhou, Chao Xie
article en

Abstract

In this work, for the first time, an MoS<sub>2</sub>/Ni<sub>3</sub>S<sub>2</sub> heterostructure (MSNS) was employed as the counter electrode. When combined with an unmodified Cu-PBA working electrode, the equilibrium adsorption capacity reached up to 579.66 mg g<sup>-1</sup> and it demonstrated high Cs<sup>+</sup> selectivity and excellent cycling stability. A detailed study indicated that the exceptional HER/OER catalytic activity of MSNS mitigated polarization and expedited electron transfer, thereby augmenting the electrochemical Cs<sup>+</sup> extraction performance.

Chemical CommunicationsVol. 61(97)
Tianjin University of Science and Technology (CN), Nankai University (CN)
Openalex Percentile: Top 60%
Chemical Synthesis and Characterization
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