Correlation Development for Para-to-Ortho Hydrogen Catalytic Conversion in Vapor-Cooled Shields of Hydrogen Tanks

The cooling effect from the para-ortho hydrogen conversion (POC) combined with a vapor-cooled shield (VCS) and multi-layer insulation (MLI) can effectively extend the storage duration of liquid hydrogen in cryogenic tanks. However, there is currently no effective and straightforward empirical correlation available for predicting the catalytic POC efficiency in VCS pipelines. This study focuses on the development of correlations for the catalytic conversion of para-hydrogen to ortho-hydrogen in pipelines, particularly in the context of cryogenic hydrogen storage systems. A model that incorporates the Langmuir adsorption characteristics of catalysts and introduces the concept of conversion efficiency to quantify the catalytic process’s performance is introduced. Experimental data were obtained in the temperature range of 141.9~229.9 K from a cryogenic hydrogen catalytic conversion facility, where the effects of temperature, pressure, and flow rate on the catalytic conversion efficiency were analyzed. Based on a validation against the experimental data, the proposed model offers a reliable method for predicting the cooling effects and optimizing the catalytic conversion process in VCS pipelines, which may contribute to the improvement of liquid hydrogen storage systems, enhancing both the efficiency and duration of storage.