Ligand-responsive ON–OFF anion transport using copper-caged acylhydrazone transporters

Reversibly gated stimuli-responsive anion transport utilizing acylhydrazone-based transporters is reported. Acylhydrazone-copper complexation makes hydrazone protons unavailable for binding and transport, whilst decomplexation using Na<sub>2</sub>EDTA activates the ion transport.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04105h
Primary Topic
Molecular Sensors and Ion Detection
Type
article
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article

Ligand-responsive ON–OFF anion transport using copper-caged acylhydrazone transporters

Pinaki Talukdar, Naveen J. Roy, Manzoor Ahmad, Umesh Shivpuje
Chemical Communications
Molecular Sensors and Ion Detection
article

Ligand-responsive ON–OFF anion transport using copper-caged acylhydrazone transporters

Pinaki Talukdar, Naveen J. Roy, Manzoor Ahmad, Umesh Shivpuje
article en

Abstract

Reversibly gated stimuli-responsive anion transport utilizing acylhydrazone-based transporters is reported. Acylhydrazone-copper complexation makes hydrazone protons unavailable for binding and transport, whilst decomplexation using Na<sub>2</sub>EDTA activates the ion transport.

Chemical CommunicationsVol. 61(100)
Indian Institute of Science Education and Research Pune (IN)
Openalex Percentile: Top 69%
Molecular Sensors and Ion Detection
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