3D Modeling Study of Bubble-Driven Flow and Its Interaction with Cell Operation

A detailed three-dimensional model of carbon dioxide generation and movement beneath the anode in an aluminum electrolysis cell has been developed. By incorporation of localized current density and multiple nucleation sites, the model captures the transient behavior of the anode-cathode distance (ACD) and the deformation of the bath-metal interface (BMI) caused by bubble dynamics. It also evaluates the pot's response in terms of turbulent kinetic energy, providing insights into alumina dissolution efficiency and heat transfer mechanisms. The model further investigates how the MHD-induced flow direction and evacuation channel geometries impact bubble behavior, voltage fluctuations, and thermal distribution. The results not only align with existing experimental data but also shed light on subtle interplays within the cell environment. Notably, the orientation of the MHD flow emerges as a decisive factor in the local bubble overvoltage and the heterogeneity of alumina mixing. This study provides industry with actionable insights into optimizing cell design parameters by taking into consideration the impact caused by their operational ACD range, the evacuation channel width, and the relative MHD flow direction.

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Publication Details

Journal
ACS Omega
Published
2025-11-06
DOI
https://doi.org/10.1021/acsomega.5c09258
Primary Topic
Molten salt chemistry and electrochemical processes
Type
article
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article

3D Modeling Study of Bubble-Driven Flow and Its Interaction with Cell Operation

Sébastien Guérard, Jean‐François Bilodeau, Thomas Roger, László I. Kiss et al.
ACS Omega
Molten salt chemistry and electrochemical processes
article

3D Modeling Study of Bubble-Driven Flow and Its Interaction with Cell Operation

Sébastien Guérard, Jean‐François Bilodeau, Thomas Roger, László I. Kiss, Simon‐Olivier Tremblay, Lukas Dion, Samuel Théberge
article en

Abstract

A detailed three-dimensional model of carbon dioxide generation and movement beneath the anode in an aluminum electrolysis cell has been developed. By incorporation of localized current density and multiple nucleation sites, the model captures the transient behavior of the anode-cathode distance (ACD) and the deformation of the bath-metal interface (BMI) caused by bubble dynamics. It also evaluates the pot's response in terms of turbulent kinetic energy, providing insights into alumina dissolution efficiency and heat transfer mechanisms. The model further investigates how the MHD-induced flow direction and evacuation channel geometries impact bubble behavior, voltage fluctuations, and thermal distribution. The results not only align with existing experimental data but also shed light on subtle interplays within the cell environment. Notably, the orientation of the MHD flow emerges as a decisive factor in the local bubble overvoltage and the heterogeneity of alumina mixing. This study provides industry with actionable insights into optimizing cell design parameters by taking into consideration the impact caused by their operational ACD range, the evacuation channel width, and the relative MHD flow direction.

ACS OmegaVol. 10(45)
Université du Québec à Chicoutimi (CA), Rio Tinto (Canada) (CA)
Openalex Percentile: Top 70%
Molten salt chemistry and electrochemical processes
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