Specific Features of Single Crystals of Tris(ethylenediamine)nickel(II) Dichloride Dihydrate in the Temperature Range of 85–293 K
The effect of the temperature on the single-crystal structure of tris(ethylenediamine)nickel(II) dichloride dihydrate [Ni(en)3]Cl2⋅2H2O, or [Ni(H2NCH2CH2NH2)3]Cl2⋅2H2O, was investigated. The rearrangement of the structure with decreasing temperature from 293 to 85 K was studied by X-ray diffraction analysis. A threefold decrease in the unit cell volume of the crystal was observed, while sp. gr. С2/с was retained.
Authors
- N. E. Novikova (ORCID: https://orcid.org/0000-0002-7744-9135)
- Н. И. Сорокина (ORCID: https://orcid.org/0000-0002-9105-9272)
- В. А. Коморников (ORCID: https://orcid.org/0000-0001-8965-7604)
- И. А. Верин
Institutions
- Kurchatov Institute (RU)
- A.V. Shubnikov Institute of Crystallography (RU)
Publication Details
- Journal
- Crystallography Reports
- Published
- 2025-10-01
- DOI
- https://doi.org/10.1134/s1063774525600966
- Primary Topic
- Thermal and Kinetic Analysis
- Type
- article
- Field-Weighted Citation Impact
- 0.00