Phosphorus chirality assignment and solution dynamics of lanthanide( <scp>iii</scp> ) complexes of a monomethylphosphinate analogue of H <sub>4</sub> dota: a multinuclear NMR and DFT study
Orientation of the substituents of the coordinated phosphinate group was experimentally determined for the first time and exchange between its coordinated/non-coordinated oxygen atoms (“phosphinate rotation”) was experimentally/computationally confirmed.
Authors
- Jan Kotek (ORCID: https://orcid.org/0000-0003-1777-729X)
- Petr Hermann (ORCID: https://orcid.org/0000-0001-6250-5125)
- Carlos Platas‐Iglesias (ORCID: https://orcid.org/0000-0002-6989-9654)
- Adam Svítok
Institutions
- Universidade da Coruña (ES)
- Charles University (CZ)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-11-06
- DOI
- https://doi.org/10.1039/d5qi01885d
- Citations
- 1
- Primary Topic
- Lanthanide and Transition Metal Complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.52
Funders
- Univerzita Karlova v Praze
- Grantová Agentura České Republiky