The effect of the large cation matrix and delocalization of electronic density on the switchable behaviour of heterotrimetallic cyanido-bridged Fe <sub> <i>x</i> </sub> Mn <sub> 9− <i>x</i> </sub> W <sub>6</sub> clusters
A Mn( ii )-cation-based large matrix stabilizes the HT phase and shapes the phase transitions and spin-state equilibria in a trimetallic {FeIIxMnII9−x[W V (CN) 8 ] 6 (MeOH) 24 }· n MeOH cluster series.
Authors
- Ján Michalík (ORCID: https://orcid.org/0000-0002-6019-3532)
- Katarzyna Dziedzic-Kocurek (ORCID: https://orcid.org/0000-0002-1566-7217)
- Barbara Sieklucka (ORCID: https://orcid.org/0000-0003-3211-5008)
- Magdalena Fitta (ORCID: https://orcid.org/0000-0001-9500-4503)
- Dawid Pinkowicz (ORCID: https://orcid.org/0000-0002-9958-3116)
- Jędrzej Kobylarczyk (ORCID: https://orcid.org/0000-0002-1745-3562)
- Robert Podgajny (ORCID: https://orcid.org/0000-0001-7457-6799)
- Marcin Kozieł (ORCID: https://orcid.org/0000-0002-9606-7642)
Institutions
- Jagiellonian University (PL)
- Institute of Physics (PL)
- Institute of Nuclear Physics, Polish Academy of Sciences (PL)
- AGH University of Krakow (PL)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-11-05
- DOI
- https://doi.org/10.1039/d5qi01515d
- Citations
- 1
- Primary Topic
- Inorganic Chemistry and Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.54