Competing hydrogen bonding and acyclic π-stacking between hydrogen-bridged quasi-rings in <i>Z</i> - and <i>E</i> -methyl pyruvate semicarbazone: a quantitative interaction energy analysis
Crystallographic and energetic analyses show how E / Z isomers form distinct supramolecular architectures. Hydrogen bonding and dispersion govern assembly, with energy vector diagrams revealing interaction hierarchies in acyclic systems.
Authors
- Niko S. Radulović (ORCID: https://orcid.org/0000-0003-1342-7567)
- Vukadin M. Leovac (ORCID: https://orcid.org/0000-0003-3551-6034)
- Vidak Raičević (ORCID: https://orcid.org/0000-0002-3858-4350)
- Nemanja Banić (ORCID: https://orcid.org/0000-0003-1272-8499)
- Marko V. Rodić (ORCID: https://orcid.org/0000-0002-4471-8001)
Institutions
- University of Nis (RS)
- University of Novi Sad (RS)
Publication Details
- Journal
- CrystEngComm
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ce00911a
- Primary Topic
- Crystallography and molecular interactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00