Rapid copper( <scp>i</scp> )-catalyzed synthesis of <i>p</i> -benzoquinone within minutes using a Keggin-type POM dimer-based metal–organic complex
A novel Cu( i )-based POMOC catalyzes the selective oxidation of 2,3,6-trimethylphenol to TMBQ, reaching 99% conversion and 97% selectivity in merely 4 minutes with a remarkable TOF of 4125 h − ¹.
Authors
- Na Xu (ORCID: https://orcid.org/0000-0001-7447-4581)
- Ying Hui Sun (ORCID: https://orcid.org/0000-0002-2570-9206)
- Zhong Zhang (ORCID: https://orcid.org/0000-0001-8749-5277)
- Xiuli Wang (ORCID: https://orcid.org/0000-0002-0308-1403)
Institutions
- Nankai University (CN)
- Bohai University (CN)
Publication Details
- Journal
- Journal of Materials Chemistry A
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5ta07782f
- Citations
- 8
- Primary Topic
- Metal-Organic Frameworks: Synthesis and Applications
- Type
- article
- Field-Weighted Citation Impact
- 4.30