Electrochemical Anodic Oxidation Treatment of Pool Water Containing Cyanuric Acid

Cyanuric acid (CYA) is widely used as a chlorine stabilizer in swimming pools, but concentrations above 75 mg L−1 cause overstabilization and loss of disinfection capacity. This study evaluated CYA removal by advanced oxidation processes, including heterogeneous photocatalysis, photo-Fenton, photo-persulfate, and anodic oxidation (AO). AO with boron-doped diamond anodes proved most effective, achieving up to 90% total organic carbon removal in ultrapure water. When applied to real swimming pool samples (118 and 251 mg L−1 CYA), the process achieved significant CYA abatement, demonstrating its potential as a practical strategy to control overstabilization without additional chemicals.

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Publication Details

Journal
Pollutants
Published
2025-11-03
DOI
https://doi.org/10.3390/pollutants5040039
Primary Topic
Advanced oxidation water treatment
Type
article
Field-Weighted Citation Impact
0.00

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article

Electrochemical Anodic Oxidation Treatment of Pool Water Containing Cyanuric Acid

José A. Casas, Inês Gomes, Juan A. Zazo, Lurdes Ciríaco et al.
Pollutants
Advanced oxidation water treatment
article

Electrochemical Anodic Oxidation Treatment of Pool Water Containing Cyanuric Acid

José A. Casas, Inês Gomes, Juan A. Zazo, Lurdes Ciríaco, Jefferson E. Silveira, Alicia L. García-Costa, Annabel Fernandes, Jaime Carbajo
article en

Abstract

Cyanuric acid (CYA) is widely used as a chlorine stabilizer in swimming pools, but concentrations above 75 mg L−1 cause overstabilization and loss of disinfection capacity. This study evaluated CYA removal by advanced oxidation processes, including heterogeneous photocatalysis, photo-Fenton, photo-persulfate, and anodic oxidation (AO). AO with boron-doped diamond anodes proved most effective, achieving up to 90% total organic carbon removal in ultrapure water. When applied to real swimming pool samples (118 and 251 mg L−1 CYA), the process achieved significant CYA abatement, demonstrating its potential as a practical strategy to control overstabilization without additional chemicals.

PollutantsVol. 5(4)
Universidad Complutense de Madrid (ES), University of Beira Interior (PT), Universidad Autónoma de Madrid (ES)
Ministerio de Ciencia, Innovación y Universidades, Ministério da Ciência, Tecnologia e Ensino Superior, Fundação para a Ciência e a Tecnologia
Openalex Percentile: Top 70%
Advanced oxidation water treatment
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