Spontaneous Emission from Electronic Metastable Resonance States

We demonstrate that calculating the spontaneous emission decay rate from metastable resonance states (states with finite lifetimes embedded in the continuum) requires considering transitions to all continuum states, not just to lower states. This holds even when the lifetimes of the metastable states are very long and might be effectively considered as bound states in the continuum. However, employing complex-scaling transformations, this computationally prohibitive task becomes feasible by utilizing methods originally designed for excited bound states for calculation of complex poles of the scattering matrix. As an illustrative example, these methods are applied to calculate the spontaneous emission decay rates of metastable resonance states in a double-barrier potential. The rapid numerical convergence of this approach highlights a new avenue for studying spontaneous emission from metastable states in real-life systems, particularly in many-electron systems, where calculation of the spontaneous emission decay rate from metastable resonances (e.g., autoionization states) is computationally difficult, if not impossible, using the standard (Hermitian) formalism of quantum mechanics.