Synthesis and Сharacterization of Novel Fluorescein-Based Surfactants

In this study, a series of surfactants containing fluorescein, alkyl fragments, and a polar imidazolium polar group were synthesized. The aggregation properties of the compounds in aqueous buffer solutions were studied using fluorescence and Nanoparticle Tracking Analysis (NTA), which allowed the critical micelle concentration and the size of the associates to be determined, respectively. The quantum yields of the obtained surfactants were determined by a relative method. It was demonstrated that the surfactant containing an octyl fragment exhibits a high quantum yield of up to 78%.

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Publication Details

Journal
Russian Journal of General Chemistry
Published
2025-10-01
DOI
https://doi.org/10.1134/s1070363225605423
Primary Topic
Surfactants and Colloidal Systems
Type
article
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article

Synthesis and Сharacterization of Novel Fluorescein-Based Surfactants

Alina А. Аrtemenko, В. А. Бурилов, Artur Khannanov, S. Е. Solovieva et al.
Russian Journal of General Chemistry
Surfactants and Colloidal Systems
article

Synthesis and Сharacterization of Novel Fluorescein-Based Surfactants

Alina А. Аrtemenko, В. А. Бурилов, Artur Khannanov, S. Е. Solovieva, Igor S. Antipin, Elza D. Sultanova, Ekaterina A. Bondareva
article en

Abstract

In this study, a series of surfactants containing fluorescein, alkyl fragments, and a polar imidazolium polar group were synthesized. The aggregation properties of the compounds in aqueous buffer solutions were studied using fluorescence and Nanoparticle Tracking Analysis (NTA), which allowed the critical micelle concentration and the size of the associates to be determined, respectively. The quantum yields of the obtained surfactants were determined by a relative method. It was demonstrated that the surfactant containing an octyl fragment exhibits a high quantum yield of up to 78%.

Russian Journal of General ChemistryVol. 95(10)
Kazan Federal University (RU), A.E. Arbuzov Institute of Organic and Physical Chemistry (RU)
Openalex Percentile: Top 76%
Surfactants and Colloidal Systems
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