Impurity-induced spin density wave in the thermoelectric layered cobaltite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mo>[</mml:mo> <mml:msub> <mml:mi>Ca</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mm

We investigate the Sn-substitution effect on the thermoelectric transport properties of the layered cobaltite ${[{\mathrm{Ca}}_{2}{\mathrm{CoO}}_{3}]}_{0.62}[{\mathrm{CoO}}_{2}]$ single crystals, which exhibit a nonmonotonic temperature variation of the electrical resistivity and the Seebeck coefficient owing to the complex electronic and magnetic states. We find that the onset temperature of the short-range spin-density-wave (SDW) formation increases with the substituted Sn content, indicating the impurity-induced stabilization of the SDW order, reminiscent of the disorder/impurity-induced spin order in the cuprate superconductors. The Seebeck coefficient is well related to such impurity effects, as it is slightly enhanced below the onset temperatures, implying a decrease in the carrier concentration due to a pseudogap formation associated with the SDW ordering. We discuss the site-dependent substitution effects including earlier studies, and suggest that substitution to the conducting ${\mathrm{CoO}}_{2}$ layers is essential to increase the onset temperature, consistent with the impurity-induced SDW picture realized in the conducting layers with the cylindrical Fermi surface.

Authors

Institutions

Publication Details

Journal
Physical Review Materials
Published
2025-10-31
DOI
https://doi.org/10.1103/q6tk-52dc
Citations
1
Primary Topic
Advanced Thermoelectric Materials and Devices
Type
article
Field-Weighted Citation Impact
0.52

Funders

Controls
|||
ALL TIME
JAN
FEB
MAR
APR
MAY
JUN
JUL
AUG
SEP
OCT
article

Impurity-induced spin density wave in the thermoelectric layered cobaltite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mo>[</mml:mo> <mml:msub> <mml:mi>Ca</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mm

Miyuki Takenaka, R. OKAZAKI, Shogo Yoshida, Yoshiki J. Sato
1 citations
Physical Review Materials
Advanced Thermoelectric Materials and Devices
0.52
article

Impurity-induced spin density wave in the thermoelectric layered cobaltite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mo>[</mml:mo> <mml:msub> <mml:mi>Ca</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mm

Miyuki Takenaka, R. OKAZAKI, Shogo Yoshida, Yoshiki J. Sato
article en
1 citations

Abstract

We investigate the Sn-substitution effect on the thermoelectric transport properties of the layered cobaltite ${[{\mathrm{Ca}}_{2}{\mathrm{CoO}}_{3}]}_{0.62}[{\mathrm{CoO}}_{2}]$ single crystals, which exhibit a nonmonotonic temperature variation of the electrical resistivity and the Seebeck coefficient owing to the complex electronic and magnetic states. We find that the onset temperature of the short-range spin-density-wave (SDW) formation increases with the substituted Sn content, indicating the impurity-induced stabilization of the SDW order, reminiscent of the disorder/impurity-induced spin order in the cuprate superconductors. The Seebeck coefficient is well related to such impurity effects, as it is slightly enhanced below the onset temperatures, implying a decrease in the carrier concentration due to a pseudogap formation associated with the SDW ordering. We discuss the site-dependent substitution effects including earlier studies, and suggest that substitution to the conducting ${\mathrm{CoO}}_{2}$ layers is essential to increase the onset temperature, consistent with the impurity-induced SDW picture realized in the conducting layers with the cylindrical Fermi surface.

Physical Review MaterialsVol. 9(10)
Tokyo University of Science (JP)
Japan Society for the Promotion of Science
Openalex Percentile: Top 31%
Advanced Thermoelectric Materials and Devices
0.52
AI Navigator

Ask Laika to Summarize, Analyze, and Connect papers live on the map.

Summarize Papers & Methodologies

Extract key findings, datasets, and comparative methods across publications.

Benchmark Rankings & Visual Analytics

Rank top research institutions, authors, funders, topics, and journals by Field-Weighted Citation Impact (FWCI) and paper volume with instant charts.

Connect Distant Disciplines

Bridge topological clusters on the map to find hidden collaborative intersections.

Impurity-induced spin density wave in the thermoelectric layered cobaltite <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:mrow> <mml:msub> <mml:mrow> <mml:mo>[</mml:mo> <mml:msub> <mml:mi>Ca</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mm — Miyuki Takenaka, R. OKAZAKI, et al. · Physical Review Materials (2025) | TGRS Research Map | TGRS