Enhanced production of dimethyl carbonate from the alternating polarity electrolysis of methanol and carbon dioxide

Alternating polarity enhanced redox-neutral electrochemical formation of dimethyl carbonate (DMC) from CO 2 and methanol. Alternating the polarity was found to be necessary for efficient reoxidation of Pd 0 → Pd 2+ thus enabling higher yields of DMC.

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Publication Details

Journal
Green Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5gc02358k
Primary Topic
Carbon dioxide utilization in catalysis
Type
article
Field-Weighted Citation Impact
0.00

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article

Enhanced production of dimethyl carbonate from the alternating polarity electrolysis of methanol and carbon dioxide

Paul T. Anastas, Hanno C. Erythropel, Julie B. Zimmerman, Heather O. LeClerc et al.
Green Chemistry
Carbon dioxide utilization in catalysis
article

Enhanced production of dimethyl carbonate from the alternating polarity electrolysis of methanol and carbon dioxide

Paul T. Anastas, Hanno C. Erythropel, Julie B. Zimmerman, Heather O. LeClerc, Ho Yan Gloria Tse, Darren S. Lee, Momoko Ishii, Maria Maigaard Paulsen, Remi A. Mellinghoff
article en

Abstract

Alternating polarity enhanced redox-neutral electrochemical formation of dimethyl carbonate (DMC) from CO 2 and methanol. Alternating the polarity was found to be necessary for efficient reoxidation of Pd 0 → Pd 2+ thus enabling higher yields of DMC.

Green ChemistryVol. 27(45)
Yale University (US), Yale New Haven Health System (US), Nottingham Trent University (GB), Aalborg University (DK)
Yale University, Nottingham Trent University, Trent University, Department of Geology and Geophysics, Yale University
Openalex Percentile: Top 76%
Carbon dioxide utilization in catalysis
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Enhanced production of dimethyl carbonate from the alternating polarity electrolysis of methanol and carbon dioxide — Paul T. Anastas, Hanno C. Erythropel, et al. · Green Chemistry (2025) | TGRS Research Map | TGRS