Inversion of circularly polarized luminescence in chiral PIM membranes <i>via</i> co-assembly with achiral perovskite quantum dots

A pair of chiral polymers of intrinsic microporosity, denoted as (+)/(-)-CCS-PIM, were synthesized with robust circularly polarized luminescence (CPL). Co-assembly of chiral CCS-PIMs with achiral CsPbBr<sub>3</sub> quantum dots achieves CPL handedness inversion without emission shift. This simple strategy expands the tunability of hybrid chiroptical materials, offering new design principles for optoelectronic applications.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc05486a
Primary Topic
Synthesis and Properties of Aromatic Compounds
Type
article
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article

Inversion of circularly polarized luminescence in chiral PIM membranes via co-assembly with achiral perovskite quantum dots

Shi‐Peng Sun, Qiang Chen, Zhuang Liu, Xinbo Wang et al.
Chemical Communications
Synthesis and Properties of Aromatic Compounds
article

Inversion of circularly polarized luminescence in chiral PIM membranes via co-assembly with achiral perovskite quantum dots

Shi‐Peng Sun, Qiang Chen, Zhuang Liu, Xinbo Wang, W. Zhou
article en

Abstract

A pair of chiral polymers of intrinsic microporosity, denoted as (+)/(-)-CCS-PIM, were synthesized with robust circularly polarized luminescence (CPL). Co-assembly of chiral CCS-PIMs with achiral CsPbBr<sub>3</sub> quantum dots achieves CPL handedness inversion without emission shift. This simple strategy expands the tunability of hybrid chiroptical materials, offering new design principles for optoelectronic applications.

Chemical CommunicationsVol. 61(96)
Shanghai University (CN), Shandong University (CN), Suzhou University of Science and Technology (CN), Ingenierie des Materiaux polymeres (FR), Shanghai Research Institute of Materials (CN)
Openalex Percentile: Top 76%
Synthesis and Properties of Aromatic Compounds
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Inversion of circularly polarized luminescence in chiral PIM membranes <i>via</i> co-assembly with achiral perovskite quantum dots — Shi‐Peng Sun, Qiang Chen, et al. · Chemical Communications (2025) | TGRS Research Map | TGRS