Convergent paths: a metal-free carbon nanozyme for highly efficient ascorbic acid oxidation

A metal-free N-doped carbon nanozyme was prepared employing an ionic conjugated porous polymer as the pyrolysis precursor. It exhibits excellent dual enzyme-like activity toward the oxidation of ascorbic acid, along with exceptional stability. Mechanistic studies reveal a kinetic-dependent dual role (antioxidant/pro-oxidant) of ascorbic acid in the nanozyme-mediated oxidation reaction.

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Publication Details

Journal
Chemical Communications
Published
2025-01-01
DOI
https://doi.org/10.1039/d5cc04574f
Primary Topic
Advanced Nanomaterials in Catalysis
Type
article
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article

Convergent paths: a metal-free carbon nanozyme for highly efficient ascorbic acid oxidation

Yaling Tao, Ting Hou, L. Zhang, Feng Li et al.
Chemical Communications
Advanced Nanomaterials in Catalysis
article

Convergent paths: a metal-free carbon nanozyme for highly efficient ascorbic acid oxidation

Yaling Tao, Ting Hou, L. Zhang, Feng Li, Mengli Zhang, Dangqiang Zhu
article en

Abstract

A metal-free N-doped carbon nanozyme was prepared employing an ionic conjugated porous polymer as the pyrolysis precursor. It exhibits excellent dual enzyme-like activity toward the oxidation of ascorbic acid, along with exceptional stability. Mechanistic studies reveal a kinetic-dependent dual role (antioxidant/pro-oxidant) of ascorbic acid in the nanozyme-mediated oxidation reaction.

Chemical CommunicationsVol. 61(94)
Qingdao Agricultural University (CN)
Openalex Percentile: Top 75%
Advanced Nanomaterials in Catalysis
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