Effects of Contamination on the Recyclability of NdFeB Permanent Magnets via Short-Loop Processing: Review of Common Contaminants and Study on Ni Coating Residues

Short-loop recycling of NdFeB trades a reduced ecological burden for a higher sensitivity towards contamination, as the powder is usually further processed as-is. In this investigation, the known effects of common contaminants (O, C, Ni, Cu, and Zn) introduced due to product design choices, namely from coating material and adhesive residue or a lack of corrosion protection, are reviewed. This study focuses on the impact of such contaminants on the magnetic properties and microstructure of recycled magnets via HPMS and re-sintering. Because of the lack of information regarding the practical effects of metallic coating residues, the impact of Ni contamination on the properties of re-sintered NdFeB magnets is assessed. HPMS processed scrap powder is blended with Ni powder and recycled by sintering. It is found that Ni partially substitutes Fe in the φ-phase, as expected from the literature review, leading to detrimental effects on the coercivity and remanence. The formation of an α-(Fe, Ni) phase is observed. The acceptable limit of Ni contamination without detrimental effects is found to be around 0.25 wt.%; however, due to the substitution in the φ-phase, the contamination is irreversible via short-loop recycling and would accumulate over multiple lifecycles.