Synthesis of <i>S</i> -allylic sulfinamides by the catalytic nucleophilic allylation of <i>N</i> -sulfinylamines

Sulfinamides are important compounds in organic synthesis and biologically active molecules, but <i>S</i>-allylic sulfinamides have received scant attention. Herein, we describe the synthesis of <i>S</i>-allylic sulfinamides by indium- or (thio)urea-catalyzed additions of allylboron reagents to <i>N</i>-sulfinylamines.

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Journal
Organic & Biomolecular Chemistry
Published
2025-01-01
DOI
https://doi.org/10.1039/d5ob01562f
Primary Topic
Sulfur-Based Synthesis Techniques
Type
article
Field-Weighted Citation Impact
0.00

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article

Synthesis of S -allylic sulfinamides by the catalytic nucleophilic allylation of N -sulfinylamines

Daniel. F. Moseley, Kevin M. Foote, Kieran D. Jones, Hon Wai Lam et al.
Organic & Biomolecular Chemistry
Sulfur-Based Synthesis Techniques
article

Synthesis of S -allylic sulfinamides by the catalytic nucleophilic allylation of N -sulfinylamines

Daniel. F. Moseley, Kevin M. Foote, Kieran D. Jones, Hon Wai Lam, Stephen P. Argent, Shamim Fanai-Danesh
article en

Abstract

Sulfinamides are important compounds in organic synthesis and biologically active molecules, but <i>S</i>-allylic sulfinamides have received scant attention. Herein, we describe the synthesis of <i>S</i>-allylic sulfinamides by indium- or (thio)urea-catalyzed additions of allylboron reagents to <i>N</i>-sulfinylamines.

Organic & Biomolecular ChemistryVol. 23(46)
University of Hertfordshire (GB), University of Nottingham (GB)
Pharmaron, Engineering and Physical Sciences Research Council
Openalex Percentile: Top 76%
Sulfur-Based Synthesis Techniques
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