Localizing tetrahedral aluminum in nitrate-bearing gibbsite to constrain defect-impurity coupling
The enhanced radiolytic stability of gibbsite (α-Al(OH) 3 ) containing trace nitrate (NO 3 − ) is a phenomenon in nuclear waste management, but its structural origins remain unresolved.
Authors
- Khashayar Ghandi (ORCID: https://orcid.org/0000-0003-1287-0081)
- Micah P. Prange (ORCID: https://orcid.org/0000-0002-0775-2024)
- Nancy Washton (ORCID: https://orcid.org/0000-0002-9643-6794)
- Trent R. Graham (ORCID: https://orcid.org/0000-0001-8907-8004)
- Gregory K. Schenter (ORCID: https://orcid.org/0000-0001-5444-5484)
- Carolyn I. Pearce (ORCID: https://orcid.org/0000-0003-3098-1615)
- Xin Zhang (ORCID: https://orcid.org/0000-0003-2000-858X)
- Jonathan David Bazak
Institutions
- Pacific Northwest National Laboratory (US)
- Washington State University (US)
- University of Guelph (CA)
Publication Details
- Journal
- Inorganic Chemistry Frontiers
- Published
- 2025-10-29
- DOI
- https://doi.org/10.1039/d5qi01703c
- Primary Topic
- Nuclear materials and radiation effects
- Type
- article
- Field-Weighted Citation Impact
- 0.00
Funders
- U.S. Department of Energy
- Battelle
- Office of Science
- Biological and Environmental Research
- Laboratory Directed Research and Development
- Pacific Northwest National Laboratory