Deposition of Multilayer Nanostructured Coating Cr/(Cr/a-C)ml on Alloy Steels
A chromium/amorphous carbon (Cr/(Cr/a-C)ml) nanostructured multilayer coating with a chromium sublayer was deposited on 42CrMo4 (1.7225,BDS EN ISO 683-2:2018), 100Cr6 (1.3505, BDS EN ISO 683-17:2024), and HS18-0-1 (1.3355, BDS EN ISO 4957:2018) alloy steels, selected for their use in contact-loaded components subjected to cyclic fatigue and intense wear. The coating was sputter deposited by MF pulsed magnetron sputtering under consistent process parameters. The resulting coating, approximately 1.8 μm thick, can significantly enhance the service life of these components. Adhesion was evaluated via the Daimler-Benz test, while coating homogeneity was confirmed through energy-dispersive spectroscopy, revealing a consistent chemical composition across sample surfaces. Raman spectroscopy indicated a high sp<sup>3</sup>/sp<sup>2</sup> ratio, confirming a dominant diamond-like carbon structure. Nanoindentation measurements verified the coating's hardness, aligning with the observed structural properties. These results validate the process parameters for depositing a Cr/(Cr/a-C)ml coating on these alloy steels, achieving this study's objectives.
Authors
- Antonio Nikolov (ORCID: https://orcid.org/0000-0003-1768-1028)
- Yavor Sofronov (ORCID: https://orcid.org/0000-0001-9056-6056)
- Valentin Mishev (ORCID: https://orcid.org/0000-0002-0547-637X)
- Boyan Dochev (ORCID: https://orcid.org/0000-0001-9587-5114)
- Milko Yordanov (ORCID: https://orcid.org/0009-0006-5405-8736)
- Krassimir Marchev (ORCID: https://orcid.org/0009-0004-1082-2988)
- Georgi Dimitrov Todorov (ORCID: https://orcid.org/0000-0002-2381-7449)
- Милко Ангелов (ORCID: https://orcid.org/0009-0000-1532-5295)
- Krum Petrov (ORCID: https://orcid.org/0009-0002-0620-5069)
Institutions
- Northeastern University (US)
- Technical University of Sofia (BG)
- University of Food Technologies (BG)
Publication Details
- Journal
- Materials
- Published
- 2025-10-28
- DOI
- https://doi.org/10.3390/ma18214923
- Citations
- 2
- Primary Topic
- Diamond and Carbon-based Materials Research
- Type
- article
- Field-Weighted Citation Impact
- 1.04
Funders
- European Regional Development Fund