Long-range coordination engineering in nickel single-atom catalysts to boost the electroreduction of CO <sub>2</sub>
The practical application of Ni-single atom catalysts (Ni-SACs) is hindered by their insufficient intrinsic activity. Long-range coordination engineering <i>via</i> Cl/S doping in the higher-order coordination shells (≥2) effectively modulates the electronic structure of Ni-SACs to strengthen the *COOH binding, thereby enhancing eCO<sub>2</sub>RR activity toward CO.
Authors
- Fengrui Li
- Cheng Lian (ORCID: https://orcid.org/0000-0002-9016-832X)
- Jingkun Li
- Peng Mei (ORCID: https://orcid.org/0000-0002-3128-1963)
- Honglai Liu (ORCID: https://orcid.org/0000-0002-5682-2295)
- Shengli Zhu (ORCID: https://orcid.org/0000-0002-0190-2626)
- Jing Li (ORCID: https://orcid.org/0000-0003-4727-4976)
- Mengde Kang
Institutions
- East China University of Science and Technology (CN)
- State Key Laboratory of Chemical Engineering (CN)
Publication Details
- Journal
- Chemical Communications
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cc05499k
- Primary Topic
- CO2 Reduction Techniques and Catalysts
- Type
- article
- Field-Weighted Citation Impact
- 0.00