Characterization of CO2 Adsorption Behavior in Pyrolyzed Shales for Enhanced Sequestration Applications

Mitigating climate change through the reduction of atmospheric CO₂ emissions remains a critical global priority. Solid adsorbents, particularly shales, have become promising options for CO₂ storage due to their favorable structural and chemical properties. In this study, a solid sorbent was developed by pyrolyzing shale at 800 °C under a nitrogen (N₂) atmospheric condition, yielding spent shale. The key physicochemical properties influencing CO₂ sorption were characterized using X-ray diffraction (XRD), Field Emission Scanning Electron Microscopy (FESEM), Brunauer-Emmett-Teller (BET) surface area analysis, and Temperature-Programmed Desorption (TPD). Mineralogical analysis revealed the presence of quartz, feldspars, clays, and carbonate minerals. The spent shale exhibited surface areas of 30-34 m²/g and pore diameters ranging from 3 to 10 nm. TPD results confirmed the presence of active adsorption sites, with a maximum CO₂ sorption capacity of about 1.62 mmol/g-surpassing several commercial sorbents. Adsorption behavior was best described by the Sips and Toth isotherm models (R² > 0.99), indicating multilayer and heterogeneous adsorption processes. Kinetic modeling using both pseudo-first-order and pseudo-second-order equations revealed that CO₂ uptake was governed by both diffusion and chemisorption mechanisms. These findings positioned spent shale as a low-cost, efficient sorbent for CO₂ storage, promoting circular resource utilization and advancing sustainable carbon management strategies. This novel shale-derived material offers a competitive pathway for carbon capture, storage, and sequestration applications.