Optimizing Uniformity and Mechanical Performance of Sandy Soil Through MICP Enhanced by n‐Butyl‐Thiophosphoryl Triamine (NBPT) as a Urease Inhibitor

Microbially induced calcium carbonate precipitation (MICP) has emerged as a sustainable approach for sandy soil stabilization, though its practical implementation is frequently hindered by nonuniform calcite distribution and premature pore occlusion near injection zones. In this study, the application of n‐butyl‐thiophosphoryl triamine (NBPT) as a urease inhibitor was systematically investigated to regulate MICP reaction kinetics, with dual objectives of enhancing mechanical performance and spatial homogeneity in treated sandy soils. A comprehensive experimental program involving solidified sand column specimens treated with NBPT concentrations spanning 0% to 1% (w/w urea) was conducted. Mechanical characterization through triaxial consolidated drained (CD) shear tests, hydraulic conductivity assessments, and stratified calcium carbonate quantification revealed critical dose‐dependent effects. Optimal enhancement was achieved at 0.1% NBPT concentration, yielding a maximum shear strength of 2.8 MPa and a three‐order‐of‐magnitude permeability reduction from 3 × 10 −4 to 2 × 10 −7 m/s. The spatial homogeneity of cementation products was substantially improved, as evidenced by a 121% increase in calcium carbonate content within the bottom section (from 3.8% to 8.4%) and a reduced spatial disparity to below 5% across vertical sections. Conversely, hyperinhibition effects were observed at elevated NBPT concentrations (1%), manifesting as suppressed microbial activity and compromised cementation integrity. These findings establish NBPT as an effective biochemical modulator for addressing MICP’s intrinsic heterogeneity limitations while concurrently enhancing geomechanical performance, offering critical guidance for field‐scale implementations in liquefaction mitigation and general erosion resistance. However, applications requiring ultra‐low permeability may necessitate supplementary treatment to meet stringent design thresholds.

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Publication Details

Journal
Advances in Civil Engineering
Published
2025-01-01
DOI
https://doi.org/10.1155/adce/5536484
Primary Topic
Microbial Applications in Construction Materials
Type
article
Field-Weighted Citation Impact
0.00

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article

Optimizing Uniformity and Mechanical Performance of Sandy Soil Through MICP Enhanced by n‐Butyl‐Thiophosphoryl Triamine (NBPT) as a Urease Inhibitor

Wangqing Xu, Dongming Zhou, Jing Xiang
Advances in Civil Engineering
Microbial Applications in Construction Materials
article

Optimizing Uniformity and Mechanical Performance of Sandy Soil Through MICP Enhanced by n‐Butyl‐Thiophosphoryl Triamine (NBPT) as a Urease Inhibitor

Wangqing Xu, Dongming Zhou, Jing Xiang
article en

Abstract

Microbially induced calcium carbonate precipitation (MICP) has emerged as a sustainable approach for sandy soil stabilization, though its practical implementation is frequently hindered by nonuniform calcite distribution and premature pore occlusion near injection zones. In this study, the application of n‐butyl‐thiophosphoryl triamine (NBPT) as a urease inhibitor was systematically investigated to regulate MICP reaction kinetics, with dual objectives of enhancing mechanical performance and spatial homogeneity in treated sandy soils. A comprehensive experimental program involving solidified sand column specimens treated with NBPT concentrations spanning 0% to 1% (w/w urea) was conducted. Mechanical characterization through triaxial consolidated drained (CD) shear tests, hydraulic conductivity assessments, and stratified calcium carbonate quantification revealed critical dose‐dependent effects. Optimal enhancement was achieved at 0.1% NBPT concentration, yielding a maximum shear strength of 2.8 MPa and a three‐order‐of‐magnitude permeability reduction from 3 × 10 −4 to 2 × 10 −7 m/s. The spatial homogeneity of cementation products was substantially improved, as evidenced by a 121% increase in calcium carbonate content within the bottom section (from 3.8% to 8.4%) and a reduced spatial disparity to below 5% across vertical sections. Conversely, hyperinhibition effects were observed at elevated NBPT concentrations (1%), manifesting as suppressed microbial activity and compromised cementation integrity. These findings establish NBPT as an effective biochemical modulator for addressing MICP’s intrinsic heterogeneity limitations while concurrently enhancing geomechanical performance, offering critical guidance for field‐scale implementations in liquefaction mitigation and general erosion resistance. However, applications requiring ultra‐low permeability may necessitate supplementary treatment to meet stringent design thresholds.

Advances in Civil EngineeringVol. 2025(1)
Hubei University of Arts and Science (CN)
National Natural Science Foundation of China
Openalex Percentile: Top 71%
Microbial Applications in Construction Materials
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