A New Functional Series of Mixed-Ligand Fe(III), Ga(III), and Eu(III) β-Diketonate Complexes: Evolution of Magnetic States
We have synthesized a new series of heteroleptic halogen-substituted complexes with the general formula [XL2Bipy]Cl, where L = 1-(4-fluorophenyl)-3-(4-bromophenyl)-propane-1,3-dione; Bipy = 2,2'-bipyridine; and X = Fe3+, Ga3+, Eu3+. Their structure and phase behavior have been studied and their magnetic properties have been investigated in a wide temperature range and analyzed theoretically.
Authors
- V.E. Vorobeva (ORCID: https://orcid.org/0000-0002-1337-9983)
- U. V. Chervonova (ORCID: https://orcid.org/0000-0003-0649-4737)
- Denis V. Starichenko (ORCID: https://orcid.org/0000-0001-9481-538X)
- М. С. Груздев (ORCID: https://orcid.org/0000-0001-8408-0092)
- I. V. Yatsyk (ORCID: https://orcid.org/0009-0001-9245-8988)
- A. S. Volegov (ORCID: https://orcid.org/0000-0002-0902-0636)
Institutions
- Ural Federal University (RU)
- Russian Academy of Sciences (RU)
- Kazan Scientific Center (RU)
- M.N. Mikheev Institute of Metal Physics (RU)
- Institute of Solution Chemistry (RU)
Publication Details
- Journal
- Bulletin of the Russian Academy of Sciences Physics
- Published
- 2025-10-01
- DOI
- https://doi.org/10.1134/s1062873825713029
- Primary Topic
- Magnetism in coordination complexes
- Type
- article
- Field-Weighted Citation Impact
- 0.00