W-Band EPR Study of Radicals in Calcium Gluconate

Electron paramagnetic resonance in the X and W bands is used to study mechanically activated calcium gluconate. The W-band spectrum is multicomponent and is described by contributions from two types of radicals with different g-factors: carbon radicals of δ-gluconolactone and the (Ca–OC6H11O6)*δ-GL radical. The parameters of these spectra, obtained through quantum chemical calculations, are in good agreement with experimental ones.

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Journal
Bulletin of the Russian Academy of Sciences Physics
Published
2025-10-01
DOI
https://doi.org/10.1134/s1062873825713005
Primary Topic
Luminescence Properties of Advanced Materials
Type
article
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article

W-Band EPR Study of Radicals in Calcium Gluconate

M. M. Akhmetov, R. B. Zaripov, Г. Н. Коныгин, Д. С. Рыбин et al.
Bulletin of the Russian Academy of Sciences Physics
Luminescence Properties of Advanced Materials
article

W-Band EPR Study of Radicals in Calcium Gluconate

M. M. Akhmetov, R. B. Zaripov, Г. Н. Коныгин, Д. С. Рыбин, Г. Г. Гумаров
article en

Abstract

Electron paramagnetic resonance in the X and W bands is used to study mechanically activated calcium gluconate. The W-band spectrum is multicomponent and is described by contributions from two types of radicals with different g-factors: carbon radicals of δ-gluconolactone and the (Ca–OC6H11O6)*δ-GL radical. The parameters of these spectra, obtained through quantum chemical calculations, are in good agreement with experimental ones.

Bulletin of the Russian Academy of Sciences PhysicsVol. 89(10)
Russian Academy of Sciences (RU), Kazan Scientific Center (RU), Physico-Technical Institute (RU), Udmurt Federal Research Center, Ural Branch of the Russian Academy of Sciences (RU)
Openalex Percentile: Top 75%
Luminescence Properties of Advanced Materials
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W-Band EPR Study of Radicals in Calcium Gluconate — M. M. Akhmetov, R. B. Zaripov, et al. · Bulletin of the Russian Academy of Sciences Physics (2025) | TGRS Research Map | TGRS