Pb(OH) <sub>2</sub> Precursor and La <sup>3+</sup> Doping Synergy: Polyethylene Terephthalate-Encapsulated Quantum Dot Films Achieve Low-Cost and High-Stability Backlight Display

Perovskite quantum dots (PQDs) are widely used in the backlight field of liquid crystal displays (LCDs) due to their narrow-band emission and high color purity. However, their high cost and insufficient stability seriously restrict the industrialization process. This study innovatively adopted the environmentally friendly Pb(OH)<sub>2</sub> to replace the traditional PbBr<sub>2</sub> lead source, successfully reducing the raw material cost by nearly 50%. At the same time, it significantly improved the optical performance of CsPbBr<sub>3</sub>@glass by reducing the formation of bromine vacancies. By further introducing La<sup>3+</sup>, the prepared La<sup>3+</sup>@CsPbBr<sub>3</sub>@glass achieved a PLQY increase from 48 to 86%, and maintained a PL intensity of 87% under harsh conditions (60 °C, 90% RH, and continuous exposure to 8000 nit blue light for 40 days), breaking through the stability bottleneck. The color gamut of the CsPbBr<sub>3</sub>&CsPbBr<sub>1</sub>I<sub>2</sub>@glass@PET light conversion film developed on this basis is 94.75% of the NTSC 1953 standard and 70.74% of the Rec.2020 standard. When they are applied to LCD screens, they significantly enhance color performance. It provides an efficient, stable, and low-cost industrial solution for quantum dot film technology.

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Publication Details

Journal
ACS Applied Materials & Interfaces
Published
2025-10-28
DOI
https://doi.org/10.1021/acsami.5c17962
Primary Topic
Luminescence and Fluorescent Materials
Type
article
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article

Pb(OH) 2 Precursor and La 3+ Doping Synergy: Polyethylene Terephthalate-Encapsulated Quantum Dot Films Achieve Low-Cost and High-Stability Backlight Display

Zhaoping Chen, Weidong Xiang, Jiapeng Yang, Ye He et al.
ACS Applied Materials & Interfaces
Luminescence and Fluorescent Materials
article

Pb(OH) 2 Precursor and La 3+ Doping Synergy: Polyethylene Terephthalate-Encapsulated Quantum Dot Films Achieve Low-Cost and High-Stability Backlight Display

Zhaoping Chen, Weidong Xiang, Jiapeng Yang, Ye He, Enrou Mei, Xiaojuan Liang, Yang Li, Ziyi Jiang, Xintong Cao
article en

Abstract

Perovskite quantum dots (PQDs) are widely used in the backlight field of liquid crystal displays (LCDs) due to their narrow-band emission and high color purity. However, their high cost and insufficient stability seriously restrict the industrialization process. This study innovatively adopted the environmentally friendly Pb(OH)<sub>2</sub> to replace the traditional PbBr<sub>2</sub> lead source, successfully reducing the raw material cost by nearly 50%. At the same time, it significantly improved the optical performance of CsPbBr<sub>3</sub>@glass by reducing the formation of bromine vacancies. By further introducing La<sup>3+</sup>, the prepared La<sup>3+</sup>@CsPbBr<sub>3</sub>@glass achieved a PLQY increase from 48 to 86%, and maintained a PL intensity of 87% under harsh conditions (60 °C, 90% RH, and continuous exposure to 8000 nit blue light for 40 days), breaking through the stability bottleneck. The color gamut of the CsPbBr<sub>3</sub>&CsPbBr<sub>1</sub>I<sub>2</sub>@glass@PET light conversion film developed on this basis is 94.75% of the NTSC 1953 standard and 70.74% of the Rec.2020 standard. When they are applied to LCD screens, they significantly enhance color performance. It provides an efficient, stable, and low-cost industrial solution for quantum dot film technology.

ACS Applied Materials & InterfacesVol. 17(45)
Ningbo University (CN), Wenzhou University (CN), Wenzhou Medical University (CN), Division of Materials Science and Engineering (AU)
Openalex Percentile: Top 75%
Luminescence and Fluorescent Materials
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