Pb(OH) <sub>2</sub> Precursor and La <sup>3+</sup> Doping Synergy: Polyethylene Terephthalate-Encapsulated Quantum Dot Films Achieve Low-Cost and High-Stability Backlight Display
Perovskite quantum dots (PQDs) are widely used in the backlight field of liquid crystal displays (LCDs) due to their narrow-band emission and high color purity. However, their high cost and insufficient stability seriously restrict the industrialization process. This study innovatively adopted the environmentally friendly Pb(OH)<sub>2</sub> to replace the traditional PbBr<sub>2</sub> lead source, successfully reducing the raw material cost by nearly 50%. At the same time, it significantly improved the optical performance of CsPbBr<sub>3</sub>@glass by reducing the formation of bromine vacancies. By further introducing La<sup>3+</sup>, the prepared La<sup>3+</sup>@CsPbBr<sub>3</sub>@glass achieved a PLQY increase from 48 to 86%, and maintained a PL intensity of 87% under harsh conditions (60 °C, 90% RH, and continuous exposure to 8000 nit blue light for 40 days), breaking through the stability bottleneck. The color gamut of the CsPbBr<sub>3</sub>&CsPbBr<sub>1</sub>I<sub>2</sub>@glass@PET light conversion film developed on this basis is 94.75% of the NTSC 1953 standard and 70.74% of the Rec.2020 standard. When they are applied to LCD screens, they significantly enhance color performance. It provides an efficient, stable, and low-cost industrial solution for quantum dot film technology.
Authors
- Zhaoping Chen (ORCID: https://orcid.org/0009-0004-3037-0640)
- Weidong Xiang (ORCID: https://orcid.org/0000-0001-9148-4618)
- Jiapeng Yang (ORCID: https://orcid.org/0009-0004-8901-6865)
- Ye He (ORCID: https://orcid.org/0000-0002-0783-9971)
- Enrou Mei
- Xiaojuan Liang (ORCID: https://orcid.org/0000-0003-1671-967X)
- Yang Li (ORCID: https://orcid.org/0000-0002-9544-5840)
- Ziyi Jiang (ORCID: https://orcid.org/0000-0002-4081-4776)
- Xintong Cao
Institutions
- Ningbo University (CN)
- Wenzhou University (CN)
- Wenzhou Medical University (CN)
- Division of Materials Science and Engineering (AU)
Publication Details
- Journal
- ACS Applied Materials & Interfaces
- Published
- 2025-10-28
- DOI
- https://doi.org/10.1021/acsami.5c17962
- Primary Topic
- Luminescence and Fluorescent Materials
- Type
- article
- Field-Weighted Citation Impact
- 0.00