Dynamics of phase-separated interfaces in inhomogeneous and driven mixtures
We derive effective equations of motion governing the dynamics of sharp interfaces in phase-separated binary mixtures driven by spatio-temporal modulations of their material properties. We demonstrate, in particular, that spatial heterogeneities in the surface tension induce an effective capillary force that drives the motion of interfaces, even in the absence of hydrodynamics. Applying our sharp interface model to quantify the dynamics of thermophoretic droplets, we find that their deformation and transport properties are controlled by a combination of bulk and capillary forces, whose relative strength depends on droplet size. Strikingly, we show that small thermophobic droplets - composed of a material with a positive Soret coefficient - can spontaneously migrate towards high-temperature regions as a result of capillary forces.
Authors
- Benoît Mahault (ORCID: https://orcid.org/0000-0001-9915-0233)
- Ramin Golestanian (ORCID: https://orcid.org/0000-0002-3149-4002)
- Jacopo Romano (ORCID: https://orcid.org/0009-0002-6286-654X)
Institutions
- Scuola Internazionale Superiore di Studi Avanzati (IT)
- University of Oxford (GB)
- Max Planck Institute for Dynamics and Self-Organization (DE)
Publication Details
- Journal
- Soft Matter
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5sm00625b
- Citations
- 1
- Primary Topic
- Solidification and crystal growth phenomena
- Type
- article
- Field-Weighted Citation Impact
- 0.52