Low-Dimensional VS <sub>3</sub> Synthesized at Elevated Pressure
VS<sub>3</sub>, a transition metal trichalcogenide that has not been previously reported, was successfully prepared by a high-pressure solid-state synthesis method. Its low-dimensional crystal structure, refined by Rietveld PXRD and confirmed by HR-STEM, features both uncommon V-S coordination polyhedra and S-S dimers. Preliminary characterization reveals low-moment paramagnetic behavior and a semiconducting nature.
Authors
- Stephen Zhang (ORCID: https://orcid.org/0000-0002-9337-0507)
- Guangming Cheng (ORCID: https://orcid.org/0000-0001-5852-1341)
- R. J. Cava (ORCID: https://orcid.org/0000-0002-3294-6867)
- Danrui Ni (ORCID: https://orcid.org/0000-0001-6916-1281)
- Nan Yao (ORCID: https://orcid.org/0000-0002-4081-1495)
- Ruyi Ke
Institutions
- Princeton University (US)
Publication Details
- Journal
- Inorganic Chemistry
- Published
- 2025-10-28
- DOI
- https://doi.org/10.1021/acs.inorgchem.5c04356
- Citations
- 1
- Primary Topic
- Catalysis and Oxidation Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.39