Comparative Thermal Ageing Analysis of Ester Dielectric Fluids Impregnating TUK Paper: Implications for Transformer Maintenance Standards

The increasing demand for electricity and the requirement for transformers to operate under higher loads have driven the search for new insulating materials. On the one hand, papers with enhanced thermal resistance, such as thermally upgraded kraft (TUK) papers, are being introduced; on the other, the use of ester liquids is gaining attention due to their thermal and environmental advantages. This study investigates the thermal ageing behaviour of TUK paper impregnated with five ester liquids—four natural liquids of different origin and one synthetic—subjected to accelerated ageing at 130 °C, 150 °C, and 170 °C, and compared with mineral oil as impregnating fluid as a reference. The degradation of the paper, assessed through its degree of polymerisation, was monitored alongside the evolution of key chemical, physical, and dielectric properties of the liquids. In addition to the experimental analysis, this work also examines the current maintenance standards applied to transformers operating with different insulating fluids. The results showed that while the paper degradation was similar across most of the esters, the ageing behaviour of the fluids differed significantly in terms of acidity, moisture content, interfacial tension, and dielectric dissipation factor. These discrepancies strongly influence the interpretation of fluid condition based on existing transformer maintenance standards, which may lead to inconsistent assessments when applied to ester-filled transformers. The findings highlight both the suitability of natural esters for high-temperature operation and the need to revisit condition assessment criteria in standards that were originally developed for mineral oil systems.