Flat band driven itinerant magnetism in the Co-pnictides <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msub> <mml:mi mathvariant="normal">CaCo</mml:mi> <mml:mn>2</mml:mn> </mml:msub> <mml:msub> <mml:mi mathvariant="normal">As</mml:mi
Flat bands can induce strong electron correlation effects that help stabilize both magnetic and superconducting states. Here, we carry out angle-resolved photoemission spectroscopy and density functional theory calculations to study the electronic structure of the Co-pnictides ${\mathrm{CaCo}}_{2}{\mathrm{As}}_{2}$ and ${\mathrm{LaCo}}_{2}{\mathrm{P}}_{2}$. We find that the ${k}_{z}$ Fermi topology of ferromagnetic ${\mathrm{LaCo}}_{2}{\mathrm{P}}_{2}$ is markedly two-dimensional, while the antiferromagnetic ${\mathrm{CaCo}}_{2}{\mathrm{As}}_{2}$ develops a 3D Fermi surface described by a zigzaglike band dispersion perpendicular to the Co-As plane. Furthermore, the magnetism is driven by the electronic correlations of the flat bands with ${d}_{xy}$ and ${d}_{{z}^{2}}$ orbital character at the Fermi level. Our results link the electronic dimensionality and the magnetic order and emphasize the critical role of the As-As and P-P bond strength along the $c$ direction to understand the electronic band structure and the rich phase diagram of transition metal pnictides.
Authors
- Dina Carbone (ORCID: https://orcid.org/0000-0003-1017-6213)
- M. Tallarida
- Maia G. Vergniory (ORCID: https://orcid.org/0000-0001-7336-3062)
- A. K. Kar (ORCID: https://orcid.org/0000-0002-8926-4664)
- E. Vescovo
- David Subires
- P. Gargiani
- Michael Shatruk (ORCID: https://orcid.org/0000-0002-2883-4694)
- Turgut Yilmaz (ORCID: https://orcid.org/0000-0001-7571-0937)
- J. Dai (ORCID: https://orcid.org/0000-0003-1388-6843)
- Vincent Yannello (ORCID: https://orcid.org/0000-0002-1612-0811)
- S. Blanco-Canosa (ORCID: https://orcid.org/0000-0002-4437-5846)
- Victoria M. Li
- Mikel García‐Díez (ORCID: https://orcid.org/0000-0002-5035-7767)
- Chaesung Lim
Institutions
- Florida State University (US)
- Ikerbasque (ES)
- Université de Sherbrooke (CA)
- University of the Basque Country (ES)
- Brookhaven National Laboratory (US)
- ALBA Synchrotron (Spain) (ES)
- Xiamen University Malaysia (MY)
- MAX IV Laboratory (SE)
- Donostia International Physics Center (ES)
- University of Tampa (US)
Publication Details
- Journal
- Physical review. B./Physical review. B
- Published
- 2025-09-22
- DOI
- https://doi.org/10.1103/w9rw-rjdh
- Citations
- 2
- Primary Topic
- Iron-based superconductors research
- Type
- article
- Field-Weighted Citation Impact
- 0.85