Manganese Complexes Bearing Bulky DAB Ligands as Efficient Catalysts for the Solvent-Free Hydroboration of Ketones
Manganese complexes of the general formula [Mn(DAB)(CO)<sub>3</sub>Br] featuring sterically demanding α-diimine ligands (DAB) were prepared, characterized, and found to be catalytically active in the hydroboration of ketones. The developed eco-friendly approach allowed straightforward formation of boronic esters in quantitative yields in mild and solvent-free conditions.
Authors
- Patrycja Żak (ORCID: https://orcid.org/0000-0002-9138-2416)
- Aleksandra Mermela (ORCID: https://orcid.org/0009-0005-8879-0135)
- Monika Wałęsa‐Chorab (ORCID: https://orcid.org/0000-0002-0605-6078)
- Agata Duch
Institutions
- Adam Mickiewicz University in Poznań (PL)
Publication Details
- Journal
- International Journal of Molecular Sciences
- Published
- 2025-10-28
- DOI
- https://doi.org/10.3390/ijms262110454
- Citations
- 1
- Primary Topic
- Organoboron and organosilicon chemistry
- Type
- article
- Field-Weighted Citation Impact
- 0.94