Electrochemically Catalyzed Decarboxylative Borylation of (Hetero)Aryl Carboxylic Acids
A straightforward and efficient electrochemical method for the decarboxylative borylation of (hetero)aryl carboxylic acids has been outlined. This metal-/base-/oxidant-free strategy enables efficient access to arylboronate esters, demonstrating a broad substrate scope (20 examples) with yields of up to 62% while maintaining exceptional atom- and step-economy.
Authors
- Zhanwei Xu (ORCID: https://orcid.org/0000-0003-0830-5258)
- Yan Tian (ORCID: https://orcid.org/0000-0002-7416-656X)
- Bo Xu (ORCID: https://orcid.org/0000-0001-8702-1872)
- X. KONG (ORCID: https://orcid.org/0009-0006-4378-2921)
- Yuan Yuan (ORCID: https://orcid.org/0000-0001-7877-3175)
- Yingchao Li (ORCID: https://orcid.org/0000-0003-2539-6710)
- Yucan He
Institutions
- Donghua University (CN)
- Changzhou Institute of Technology (CN)
- Changzhou Vocational Institute of Engineering (CN)
Publication Details
- Journal
- Synthesis
- Published
- 2025-10-27
- DOI
- https://doi.org/10.1055/a-2733-1592
- Primary Topic
- Radical Photochemical Reactions
- Type
- article
- Field-Weighted Citation Impact
- 0.00