Manganese single-atom modification of MOF-808 for catalytic nerve agent and simulant degradation
Single-atom Mn sites on MOF-808 catalyze sarin simulant degradation under solid, unbuffered conditions. Spectroscopic and computational results show altered product binding that mitigates poisoning and sustains reactivity.
Authors
- Diego Troya (ORCID: https://orcid.org/0000-0003-4971-4998)
- Mikaela C. Boyanich (ORCID: https://orcid.org/0000-0002-7109-0993)
- Conor Long (ORCID: https://orcid.org/0000-0002-9484-8744)
- Mohammad Khurram Javed (ORCID: https://orcid.org/0000-0001-8898-0418)
- Arshia Sulaiman (ORCID: https://orcid.org/0000-0001-6964-307X)
- Minliang Yan
- Alex Balboa
- Amanda J. Morris (ORCID: https://orcid.org/0000-0002-3512-0366)
- Carl Fossum (ORCID: https://orcid.org/0009-0003-7348-3568)
- Christopher J. Karwacki
- Jenny V. Lockard (ORCID: https://orcid.org/0000-0001-7758-169X)
- John J. Mahle
- John R. Morris (ORCID: https://orcid.org/0000-0001-9140-5211)
- Hui Wang (ORCID: https://orcid.org/0000-0002-1696-7043)
- Eric M. Johnson (ORCID: https://orcid.org/0000-0003-0507-3690)
- Naveen Kumar (ORCID: https://orcid.org/0000-0001-8585-9372)
- M. Léonard
Institutions
- Rutgers, The State University of New Jersey (US)
- United States Army Combat Capabilities Development Command (US)
- Virginia Tech (US)
Publication Details
- Journal
- Catalysis Science & Technology
- Published
- 2025-01-01
- DOI
- https://doi.org/10.1039/d5cy00940e
- Citations
- 1
- Primary Topic
- Catalytic Processes in Materials Science
- Type
- article
- Field-Weighted Citation Impact
- 0.52
Funders
- National Science Foundation
- U.S. Department of Energy
- Office of Science
- Division of Chemistry
- Army Research Office
- Brookhaven National Laboratory
- Army Research Laboratory