Dynamic change in light-regulated hardness in SrTiO3

We report our discovery of the dynamic change in light-regulated hardness in an SrTiO3 single crystal. Vickers hardness and atomic force microscope measurements reveal that the hardness is surprisingly increased and decreased with on and off irradiation for a (110), but unchanged for a (100) oriented single crystal. The dynamic change of light-regulated hardness is primarily governed by a higher concentration of photo-induced oxygen vacancies in the (110) crystal compared to the (100), as revealed by photoelectron spectroscopy. This work provides an undiscovered route toward controlling the dynamic change of hardness, which may offer alternative strategies to tune the localized deformations in polycrystalline metal oxides.

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Publication Details

Journal
Applied Physics Letters
Published
2025-10-23
DOI
https://doi.org/10.1063/5.0283875
Primary Topic
Electronic and Structural Properties of Oxides
Type
article
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article

Dynamic change in light-regulated hardness in SrTiO3

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Dynamic change in light-regulated hardness in SrTiO3

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article en

Abstract

We report our discovery of the dynamic change in light-regulated hardness in an SrTiO3 single crystal. Vickers hardness and atomic force microscope measurements reveal that the hardness is surprisingly increased and decreased with on and off irradiation for a (110), but unchanged for a (100) oriented single crystal. The dynamic change of light-regulated hardness is primarily governed by a higher concentration of photo-induced oxygen vacancies in the (110) crystal compared to the (100), as revealed by photoelectron spectroscopy. This work provides an undiscovered route toward controlling the dynamic change of hardness, which may offer alternative strategies to tune the localized deformations in polycrystalline metal oxides.

Applied Physics LettersVol. 127(17)
Synchrotron Light Research Institute (TH), Max-Planck-Institut für Nachhaltige Materialien (DE), King Mongkut's University of Technology Thonburi (TH), Naresuan University (TH), Suranaree University of Technology (TH), Silpakorn University (TH), Walailak University (TH)
Openalex Percentile: Top 76%
Electronic and Structural Properties of Oxides
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