Strong and selective magnon-phonon coupling in the van der Waals antiferromagnet <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"> <mml:msub> <mml:mi>CoPS</mml:mi> <mml:mn>3</mml:mn> </mml:msub> </mml:math>
The Raman scattering response of the biaxial antiferromagnet ${\mathrm{CoPS}}_{3}$ has been investigated as a function of both magnetic field and temperature. The peaks observed in the low-frequency spectral range $(90--200 {\mathrm{cm}}^{\ensuremath{-}1})$ have been identified as hybrid magnon-phonon excitations. The energies of the bare magnon and phonon modes and the effective coupling strengths between different excitation pairs have been determined. The strong and selective magnon-phonon interaction largely accounts for the pronounced splitting of two phononlike modes observed at 152 and 158 ${\mathrm{cm}}^{\ensuremath{-}1}$ in the antiferromagnetic phase of ${\mathrm{CoPS}}_{3}$. Based on the identification of bare magnon excitations and their magnetic-field dependence, we propose an updated set of parameters for the effective exchange $({J}_{\mathrm{eff}}=9.9 \mathrm{meV})$ and biaxial magnetic anisotropy $(D=4.3 \mathrm{meV} \text{and} E=\ensuremath{-}0.7 \mathrm{meV})$ and advocate for an apparent anisotropic $g$ factor $({\mathrm{g}}_{x} = {\mathrm{g}}_{y} = 2, {\mathrm{g}}_{z}=4)$ in the ${\mathrm{CoPS}}_{3}$ antiferromagnet.
Authors
- Dipankar Jana (ORCID: https://orcid.org/0000-0001-9935-4885)
- M. Orlita (ORCID: https://orcid.org/0000-0002-9633-507X)
- Rajesh Kumar Ulaganathan (ORCID: https://orcid.org/0000-0001-8886-6332)
- M. E. Zhitomirsky (ORCID: https://orcid.org/0000-0002-1143-2904)
- Maciej Koperski (ORCID: https://orcid.org/0000-0002-8301-914X)
- C. Faugeras (ORCID: https://orcid.org/0000-0002-9615-8739)
- Diana Václavková (ORCID: https://orcid.org/0000-0003-3116-2224)
- M. Potemski (ORCID: https://orcid.org/0000-0001-8881-6618)
- R. Sankar (ORCID: https://orcid.org/0000-0003-2817-0952)
Institutions
- Warsaw University of Technology (PL)
- National University of Singapore (SG)
- Charles University (CZ)
- Laboratoire National des Champs Magnétiques Intenses (FR)
- Institute of High Pressure Physics (PL)
- Institute of Physics, Academia Sinica (TW)
- Institut Laue-Langevin (FR)
- FZU ‒ Institute of Physics of the Academy of Sciences of the Czech Republic (CZ)
- Institut des langues et cultures d'Europe, Amérique, Afrique, Asie et Australie (FR)
- Université Grenoble Alpes (FR)
Publication Details
- Journal
- Physical review. B./Physical review. B
- Published
- 2025-09-26
- DOI
- https://doi.org/10.1103/8f92-lt57
- Citations
- 1
- Primary Topic
- 2D Materials and Applications
- Type
- article
- Field-Weighted Citation Impact
- 0.52